Synthesis and characterization of a new hybrid TiO2/SiO2 filler for lithium conducting gel electrolytes

• Authors: Mariusz Walkowiak , Monika Osińska , Teofil Jesionowski , Katarzyna Siwińska-Stefańska
• Languages of publication: EN

Abstracts

EN

This paper describes the synthesis and properties of a new type of ceramic fillers for composite polymer gel electrolytes. Hybrid TiO2-SiO2 ceramic powders have been obtained by co-precipitation from titanium(IV) sulfate solution using sodium silicate as the precipitating agent. The resulting submicron-size powders have been applied as fillers for composite polymer gel electrolytes for Li-ion batteries based on poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF/HFP) copolymeric membranes. The powders, dry membranes and gel electrolytes have been examined structurally and electrochemically, showing favorable properties in terms of electrolyte uptake and electrochemical characteristics in Li-ion cells.

Keywords

EN

Li-ion battery; Polymer gel electrolyte; PVdF/HFP; Functionalized ceramic filler

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 6
• Pages: 1311-1317

Dates

published

1 - 12 - 2010

online

8 - 10 - 2010

Contributors

author

Mariusz Walkowiak

• Institute of Non-Ferrous Metals Branch in Poznań Central Laboratory of Batteries and Cells, 61-362, Poznań, Poland

author

Monika Osińska

• Institute of Non-Ferrous Metals Branch in Poznań Central Laboratory of Batteries and Cells, 61-362, Poznań, Poland

author

Teofil Jesionowski

• Institute of Chemical Technology and Engineering, Poznań University of Technology, 60-965, Poznań, Poland

author

Katarzyna Siwińska-Stefańska

• Institute of Chemical Technology and Engineering, Poznań University of Technology, 60-965, Poznań, Poland

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Identifiers

DOI

10.2478/s11532-010-0110-3