Full-text resources of PSJD and other databases are now available in the new Library of Science.
Visit https://bibliotekanauki.pl

PL EN


Preferences help
enabled [disable] Abstract
Number of results

Journal

2010 | 8 | 5 | 1090-1096

Article title

Thermal stability and electrochemical behaviour of Tetrakis-μ-benzoatodicopper(II)

Content

Title variants

Languages of publication

EN

Abstracts

EN
Copper(II) benzoate (CuB) was synthesized and structurally characterized to have a binuclear, paddle-wheel structure. The complex was found to be thermally stable up to 230°C, and underwent four stages of decomposition, loss of CO2, C6H6, CH3CH2-OCH2CH3 and some aliphatic unsaturated organic materials. The DSC curve shows two endotherms at 80.0°C and 230.0°C respectively, indicating that the initial weight loss can be attributed to solvated molecules and the starting of the major decomposition process, (shown in the TG analysis). Cyclic voltammetry studies in a mixed-solvent system of methanol and ethanoic acid (20:1 v/v) show three cathodic peaks, at −0.13 V, −0.35 V and −0.74 V, representing a step-wise electron transfer process, and two overlapping anodic peaks at +0.31 V and +0.46 V. The high value of ΔE ranging from 400 mV to 1200 mV indicates that the redox process is accompanied by an extensive structural reorganization of the complex in the solution creating a different geometrical environment around the central copper ion. [...]

Publisher

Journal

Year

Volume

8

Issue

5

Pages

1090-1096

Physical description

Dates

published
1 - 10 - 2010
online
5 - 9 - 2010

Contributors

  • Chemistry Department, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia
  • Chemistry Department, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia

References

  • [1] J. Ploquin, Bull. Soc. Chim. France 18, 77 (1951)
  • [2] M. Kato, H.B. Jonassen, J.C. Fanning, Chem. Rev. 64, 99 (1964) http://dx.doi.org/10.1021/cr60228a003[Crossref]
  • [3] F. Hanic, J. Michalov, Acta. Crystal. 13, 299 (1960) http://dx.doi.org/10.1107/S0365110X60000753[Crossref]
  • [4] M. Inoue, M. Kishita, M. Kubo, Inorg. Chem. 3, 239 (1964) http://dx.doi.org/10.1021/ic50012a022[Crossref]
  • [5] C.S. Fountain, W.E. Hatfield, Inorg. Chem. 4, 1368 (1965) http://dx.doi.org/10.1021/ic50031a034[Crossref]
  • [6] W.E. Hatfield, C.S. Fountain, R. Whyman, Inorg. Chem. 5, 1855 (1966) http://dx.doi.org/10.1021/ic50045a004[Crossref]
  • [7] L. Strinna Erre, G. Micera, F. Cariai, G. Ciani, Inorg. Chem. 24, 2297 (1985) http://dx.doi.org/10.1021/ic00208a034[Crossref]
  • [8] M. Melnik, Coord. Chem. Rev. 36, 1 (1981) http://dx.doi.org/10.1016/S0010-8545(00)80504-4[Crossref]
  • [9] R.W. Jonathan, F.A. Kettle, J.A. Marks, J. Chem. Soc., Dalton Trans. 428 (1972)
  • [10] M. Melnik, M. Dunaj-Jurco, M. Handlovc, Inorg. Chim. Acta 86,185 (1984) http://dx.doi.org/10.1016/S0020-1693(00)83768-8[Crossref]
  • [11] B. Chen, M. Eddoudi, S.T. Hyde, M. O’Keefe, O.M. Yaghi, Science 29, 1021 (2001) http://dx.doi.org/10.1126/science.1056598[Crossref]
  • [12] N.L. Rosi, M. Eddoudi, Jahe On Kim, M. O’Keffe, O.M. Yaghi, CrystEngComm. 4(68), 401 (2002) http://dx.doi.org/10.1039/b203193k[Crossref]
  • [13] H. Li, M. Eddoudi, M. O’Keefe, O.M. Yaghi, Nature 402, 276 (1999) http://dx.doi.org/10.1038/46248[Crossref]
  • [14] U. Schatzschneider, T. Weyhermuller, E. Rentscheler, Inorg. Chim. Acta. 337, 122 (2002) http://dx.doi.org/10.1016/S0020-1693(02)01103-9[Crossref]
  • [15] W. Lewandowski, M. Kalinowska, H. Lewandowska, J. Inorg. Biochem. 99, 1407 (2005) http://dx.doi.org/10.1016/j.jinorgbio.2005.04.010[Crossref]
  • [16] S. Takamizawa. E. Nakata, T. Saito Inorg. Chem. Comm. 7, 1 (2004) http://dx.doi.org/10.1016/j.inoche.2003.09.011[Crossref]
  • [17] J. Kaizer, R. Csonka, G. Speier, M. Giorgi, M. Reglier, J. Mol. Catalysis A: Chemical 236, 12 (2005) http://dx.doi.org/10.1016/j.molcata.2005.04.006[Crossref]
  • [18] E. Repo, E. Ahlberg, L. Murtomaki, K. Kontturi, D.J. Schiffrin, Electrochimica Acta 54, 6584 (2009) http://dx.doi.org/10.1016/j.electacta.2009.06.019[Crossref]
  • [19] Y.J. Song, H. Kwak, Y.M. Lee, S.H. Kim, S.H. Lee, B.K. Park, J.Y. Jun, S.M. Yu, C. Kim, S.J. Kim, Y. Kim, Polyhedron 28, 1241 (2009) http://dx.doi.org/10.1016/j.poly.2009.02.014[Crossref]
  • [20] B.N. Figgis, R.L. Martin, J. Chem. Soc. 3837 (1956) [Crossref]
  • [21] G.A. Bain, J.F. Berry, J. Chem. Educ. 85(4), 532 (2008) http://dx.doi.org/10.1021/ed085p532[Crossref]
  • [22] T. Kawata, H. Uekusa, S. Ohba, T. Furukwa, T. Tokii, Y. Muto, Acta Cryst. B48, 253 (1992) [Crossref]
  • [23] G.B. Deacon, R.J. Philips Coordn. Chem. Rev. 33, 227 (1980) http://dx.doi.org/10.1016/S0010-8545(00)80455-5[Crossref]
  • [24] B.S. Manhas, A.K. Trikha, J. Indian Chem. Soc LIX, 315 (1982)
  • [25] M. Kato, H.B. Jonassen, J.C. Fanning, Chem. Rev. 64, 99 (1964) http://dx.doi.org/10.1021/cr60228a003[Crossref]
  • [26] S.P. Perlepes, E. Libby, W.E. Streib, K. Folting, G. Chrsitou, Polyhedron 11(8), 923 (1992) http://dx.doi.org/10.1016/S0277-5387(00)83342-2[Crossref]
  • [27] M. Inoue, M. Kishita, M. Kubo, Inorg. Chem. 3, 239 (1964) http://dx.doi.org/10.1021/ic50012a022[Crossref]
  • [28] J. Lewis, F. Mabbs, J. Chem. Soc. 3894 (1965)
  • [29] W. Ference, A. Walkow-Dziewulska, P. Sadowski, J. Therm. Anal. Cal. 82, 365 (2005) http://dx.doi.org/10.1007/s10973-005-0904-2[Crossref]
  • [30] A. Turek, J. Kobylecka, B. Ptaszynski, J. Therm. Anal. Cal. 78, 513 (2004) http://dx.doi.org/10.1023/B:JTAN.0000046115.64116.95[Crossref]
  • [31] F.Q. Wang, D.F. Weng, X.J. Zheng, J.J. Zhang, H. Mad, L.P. Jin, Inorg. Chim. Acta 360, 2029 (2007) http://dx.doi.org/10.1016/j.ica.2006.10.023[Crossref]
  • [32] M. Arshada, S. Rehmanb, S.A. Khanb, K. Masudc, N. Arshad, A. Ghani, Thermochim. Acta 364, 143 (2000) http://dx.doi.org/10.1016/S0040-6031(00)00640-7[Crossref]
  • [33] P. Kogerler, P.A.M. Williams, B.S. Parajon-Costa, E.J. Baran, L. Lezama, T. Rojo, A. Muller, Inorg. Chim. Acta 268, 239 (1998) http://dx.doi.org/10.1016/S0020-1693(97)05751-4[Crossref]
  • [34] R.S. Nicholson, I. Shain, Anal. Chem. 36, 706 (1964) http://dx.doi.org/10.1021/ac60210a007[Crossref]
  • [35] N. Raman, S. Ravichandran, C. Thagarajah, J. Chem. Sci. 116(4), 215 (2004) http://dx.doi.org/10.1007/BF02708270[Crossref]
  • [36] R.N. Patel, V.L.N Gundla, D.K. Patel Indian J. Chem. 47A, 353 (2008)
  • [37] X. Zhou, X. Meng, W. Cheng, H. Hou, M. Tang, Y. Fan, Inorg. Chim. Acta 360, 3467 (2007) http://dx.doi.org/10.1016/j.ica.2007.03.008[Crossref]

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-010-0079-y
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.