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Number of results

Journal

2010 | 8 | 5 | 992-998

Article title

Nickel and palladium complexes of enolatefunctionalised N-heterocyclic carbenes

Content

Title variants

Languages of publication

EN

Abstracts

EN
The reaction of chloroethyltrimethylsilylether with 1-methylimidazole furnishes an ionic liquid that undergoes methanolysis to crystalline 2-hydroxyethylimidazolium chloride (crystal structure presented). Conversion to defined hydroxyethylimidazol-2-ylidene nickel complexes failed, but was accomplished with 1-methyl-3-acetophenyl-imidazolium bromide. The bis(NHC⋂O−) nickel(II) chelate is formed, rather than a methallylnickel monochelate, but with nickelocene a monochelate NiCp complex was detected. The bulky 1-(2,6-diisopropylphenyl)-3-(2’-phenyl-enolato)-imidazol-2-ylidene allylpalladium chloride was obtained in pure form. Attempts to generate catalysts for ethylene oligomerization by in situ techniques have failed so far whereas P⋂O− ligands, comparable by the P-C diagonal relationship, provide active catalysts. [...]

Publisher

Journal

Year

Volume

8

Issue

5

Pages

992-998

Physical description

Dates

published
1 - 10 - 2010
online
5 - 9 - 2010

Contributors

  • Institute of Biochemistry - Inorganic Chemistry, Ernst-Moritz-Arndt-University Greifswald, D-17489, Greifswald, Germany
author
  • Institute of Biochemistry - Inorganic Chemistry, Ernst-Moritz-Arndt-University Greifswald, D-17489, Greifswald, Germany
author
  • Institute of Inorganic and Analytical Chemistry, Technical University Braunschweig, D-38106, Braunschweig, Germany
  • Institute of Biochemistry - Inorganic Chemistry, Ernst-Moritz-Arndt-University Greifswald, D-17489, Greifswald, Germany

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-010-0071-6
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