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Journal

2010 | 8 | 4 | 852-860

Article title

Crystal structures and spectral properties of new Cd(II) and Hg(II) complexes of monensic acid with different coordination modes of the ligand

Content

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EN

Abstracts

EN
The single crystal X-ray structures and the spectroscopic properties of complexes of monensic acid (C36H62O11·H2O) with toxic metal ions of Cd(II) and Hg(II) are discussed. The cadmium(II) complex (1) is of composition [Cd(C36H61O11)2(H2O)2] and crystallizes in the monoclinic system (space group P2(1), Z = 2) with a = 12.4090(8), b = 24.7688(16), c = 14.4358(11) Å, β = 91.979(7)°. Two ligand monoanions are bound in a bidentate coordination mode to Cd(II) via the carboxylate and the primary hydroxyl oxygens occupying the equatorial plane of the complex. The axial positions of the inner coordination sphere of Cd(II) are filled by two water molecules additionally engaged in intramolecular hydrogen bonds. The Hg(II) complex (2), [Hg(C36H60O11)(H2O)], crystallizes in the orthorhombic system (space group P2(1)2(1)2(1), Z = 4) with a = 12.7316(2), b = 16.4379(3), c = 18.7184(4) Å. The monensic acid reacts with Hg(II) in a tetradentate coordination manner via both oxygen atoms of the carboxylate function and oxygens of two hydroxyl groups. The twofold negative charge of the ligand is achieved by deprotonation of carboxylic and secondary hydroxyl groups located at the opposite ends of the molecule. Hg(II) is surrounded by five oxygen atoms in a distorted square pyramidal molecular geometry. [...]

Publisher

Journal

Year

Volume

8

Issue

4

Pages

852-860

Physical description

Dates

published
1 - 8 - 2010
online
17 - 6 - 2010

Contributors

  • Medical Faculty, Sofia University, Sofia, 1164, Bulgaria
  • Faculty of Chemistry, Sofia University, Sofia, 1164, Bulgaria
  • Faculty of Chemistry, Sofia University, Sofia, 1164, Bulgaria
  • Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Sofia, 1113, Bulgaria
  • Department of Analytical Chemistry, Ruhr-Universität Bochum, D-44780, Bochum, Germany
  • Department of Analytical Chemistry, Ruhr-Universität Bochum, D-44780, Bochum, Germany

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-010-0067-2
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