Synthesis, characterization, catalytic and antimicrobial studies of ruthenium(III) complexes

• Authors: Natarajan Thilagavathi , Chinnasamy Jayabalakrishnan
• Languages of publication: EN

Abstracts

EN

Ru(III) complexes of the type [RuXB(L)2] have been prepared by the reaction of 3,4-dihydropyrimidin-2(1H)-ones/thiones (HL1–HL4) with the precursors of the type [RuX3B3] where X=Cl or Br; B=PPh3 or AsPh3 and L is the deprotonated ligand. The synthesized complexes were characterized by physico-chemical methods, electrochemical and magnetic moment data. The catalytic efficiency of the complexes were examined in the oxidation of alcohols and antimicrobial studies were also carried out. [...]

Keywords

EN

Ruthenium(III); NMO; Antimicrobial activity; EPR; Cyclic voltammetry

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 4
• Pages: 842-851

Dates

published

1 - 8 - 2010

online

17 - 6 - 2010

Contributors

author

Natarajan Thilagavathi

• Department of Chemistry, Surya Engineering College, Erode-638 107, Tamil Nadu, India

author

Chinnasamy Jayabalakrishnan

• Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, 641 020, Tamil Nadu, India

References

• [1] B.R. Sarkar, R.V. Chaudhari, Catal. Surv. Asia 9, 3 (2005) http://dx.doi.org/10.1007/s10563-005-7556-x[Crossref]
• [2] S.I. Murahashi, D. Zhang, Chem. Soc. Rev. 37, 1490 (2008) http://dx.doi.org/10.1039/b706709g[Crossref]
• [3] D. Bagchi, S.J. Stohs, B.W. Downs, M. Bagchi, H.G. Preuss, Toxicology 180, 5 (2002) http://dx.doi.org/10.1016/S0300-483X(02)00378-5[Crossref]
• [4] I.M. Geraskin, M.W. Luedtke, H.M. Neu, V.N Nemykin, V.V. Zhdankin, Tetrahedron Lett. 49, 7410 (2008) http://dx.doi.org/10.1016/j.tetlet.2008.10.060[Crossref]
• [5] M. Picqueta et al., Top. Catal. 29, 3 (2004) http://dx.doi.org/10.1023/B:TOCA.0000024925.30020.a1[Crossref]
• [6] M. Rong, C. Liu, J. Han, H. Wang, Catal. Commun. 10, 362 (2009) http://dx.doi.org/10.1016/j.catcom.2008.09.009[Crossref]
• [7] A.K. Singh, N. Chaurasia, S. Rahmani, J. Srivastava, B. Singh, Catal. Lett. 95, 3 (2004) http://dx.doi.org/10.1023/B:CATL.0000027286.07404.48[Crossref]
• [8] F. Adam, I.A. Sugiarmawan, J. Porous Mater. 16, DOI:10.1007/s10934-008-9203-1(2009) [Crossref]
• [9] D. Subhas Bose, M. Sudharshan, S.W. Chavhan, Arkivoc 3, 228 (2005)
• [10] R. Hekmatshoar, M. Heidari, M.M. Heravi, B. Baghernejad, J. Korean Chem. Soc. 53, 90 (2009) [Crossref]
• [11] J.A. Garcia-Vazquez, J. Romero, A. Sousa-Pedrares, M.L. Louro, A. Sousa, J. Zubieta, J. Chem. Soc. Dalton Trans. 559 (2000) [Crossref]
• [12] N. Thilagavathi, A. Manimaran, N. Padmapriya, N. Sathya, C. Jayabalakrishnan, Trans. Met. Chem. 34, 725 (2009) http://dx.doi.org/10.1007/s11243-009-9254-4[Crossref]
• [13] A.I. Vogel, Text book of practical organic chemistry, 5th edition (Longmann, London, 1989)
• [14] J. Chatt, G. Leigh, D.M.P. Mingos, R.J. Paske, J. Chem. Soc. A 2636 (1968) [Crossref]
• [15] P. Viswanathamurthi, K. Natarajan, Indian J. Chem. 38, 797 (1999)
• [16] K. Natarajan, R.K. Poddar, U. Agarwala, J. Inorg. Nucl. Chem. 39, 431(1977) http://dx.doi.org/10.1016/0022-1902(77)80056-0[Crossref]
• [17] B. Gangadasu, P. Narender, B. China Raju, V. Jayathirtha Rao, Indian J. Chem. A 45, 1259 (2006)
• [18] C. Jayabalakrishnan, R. Karvembu, K. Natarajan, Trans. Met. Chem. 27, 790 (2002) http://dx.doi.org/10.1023/A:1020341703855[Crossref]
• [19] G. Asgedom, A. Sreedhara, J. Kivikoshi, C.P. Rao, Polyhedron 16, 643 (1997) http://dx.doi.org/10.1016/0277-5387(96)00304-X[Crossref]
• [20] C.H. Collins, P.M. Lyne, Microbial Methods (University Park Press, Baltimore, 1970)
• [21] S.I. Mostafa, N. Hadjiliadis, Trans. Met. Chem. 33, 529 (2008) http://dx.doi.org/10.1007/s11243-008-9076-9[Crossref]
• [22] A.Z. El-Sonbati, A.A. El-Bindary, A. El-Dssouky, T.M. El-Gogary, A.S. Hilali, Spectrochim. Acta A 58, 1623 (2002) http://dx.doi.org/10.1016/S1386-1425(01)00627-8[Crossref]
• [23] V.K. Sharma, S. Srivatsava, A. Srivatsava, Bioinorg. Chem. Appl., doi:10.1155/2007/68374 (2007) [Crossref]
• [24] M.M. Taqui Khan, V. Vijay Sen Reddy, Inorg. Chem. 25, 208 (1986) http://dx.doi.org/10.1021/ic00222a023[Crossref]
• [25] M. Adib, K. Ghanbary, M. Mostofi, M. Reza Ganjali, Molecules, 11, 649 (2006) http://dx.doi.org/10.3390/11080649[Crossref]
• [26] F.S. Falsone, C. Oliver Kappe, Arkivoc, 122 (2001)
• [27] M.S. Masoud, E.A. Khalil, A.M. Ramadan, Y.M. Gohar, A. Sweyllam, Spectrochim. Acta A 67, 669 (2007) http://dx.doi.org/10.1016/j.saa.2006.07.047[Crossref]
• [28] A. Z. El-Sonbati, A.A. El-Bindary, A.F. Shoair, Spectrochim. Acta 58, 3003 (2002) http://dx.doi.org/10.1016/S1386-1425(02)00082-3[Crossref]
• [29] R. Raveendran, S. Pal, J. Organomet. Chem. 692, 824 (2007) http://dx.doi.org/10.1016/j.jorganchem.2006.10.026[Crossref]
• [30] T. Hashimoto, S. Hara, Y. Shiraishi, M. Yamauchi, K. Natarajan, K. Shimizu, Inorg. Chim. Acta 358, 2207 (2005) http://dx.doi.org/10.1016/j.ica.2005.01.005[Crossref]
• [31] K. Vijayasri, J. Rajaram, J.C. Kuriacose, J. Mol. Catal. 39, 203 (1987) http://dx.doi.org/10.1016/0304-5102(87)80064-0[Crossref]
• [32] M. Hasan, M. Musawir, P.N. Davey, I.V. Kozhevnikov, J. Mol. Catal. A Chem. 180, 77 (2002) http://dx.doi.org/10.1016/S1381-1169(01)00410-1[Crossref]
• [33] P.K. Bhattacharya, Proc. Indian Acad. Sci. (Chem. Sci.) 102, 247 (1990)
• [34] P. Paraskevopoulou, N. Psaroudakis, S. Koinis, P. Stavropoulos, K. Mertis, J. Mol. Catal. Chem. 240, 27 (2005)
• [35] M.V. Kaveri, R. Prabhakaran, R. Karvembu, K. Natarajan, Spectrochim. Acta A 61, 2915 (2005) http://dx.doi.org/10.1016/j.saa.2004.11.001[Crossref]
• [36] S. Chandra, S. Raizada, M. Tyagi, A. Gautham, Bioinorg. Chem. Appl., doi: 10.1155 / 2007 / 51483 (2007) [Crossref]

Identifiers

DOI

10.2478/s11532-010-0045-8