Sonochemical synthesis and chracterization of Mn3O4 nanoparticles

• Authors: Abdulhadi Baykal , Hüseyin Kavas , Zehra Durmuş , Mine Demir , Sinan Kazan , Ramazan Topkaya , Muhammet Toprak
• Languages of publication: EN

Abstracts

EN

We report on the synthesis of Mn3O4 nanoparticles (NPs) using a novel sonochemical method without requiring any pH adjustment. Synthesized material was identified as tetragonal hausmannite crystal structure model of Mn3O4 from XRD analysis. Crystallite size was estimated from x-ray line profile fitting to be 17±5 nm. FTIR analysis revealed stretching vibrations of metal ions in tetrahedral and octahedral coordination confirming the crystal structure. TEM analysis revealed a dominantly cubic morphology of NPs with an average size of ∼20 nm. Magnetic evaluation revealed a blocking temperature, T B of 40 K above which the material behaves paramagnetic. Asymmetric coercive field is attributed to the interaction between ferromagnetic Mn3O4 and antiferromagnetic Mn oxide at the surface of nanoparticles. [...]

Keywords

EN

Sonochemistry; Mn3O4 ; Nanomaterials; Coercive Field; Chemical Synthesis

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 3
• Pages: 633-638

Dates

published

1 - 6 - 2010

online

25 - 4 - 2010

Contributors

author

Abdulhadi Baykal

• Department of Chemistry, Fatih University, B.Çekmece, 34500, Istanbul, Turkey

author

Hüseyin Kavas

• Department of Physics, Fatih University, B.Çekmece, 34500, Istanbul, Turkey

author

Zehra Durmuş

• Department of Chemistry, Fatih University, B.Çekmece, 34500, Istanbul, Turkey

author

Mine Demir

• Department of Chemistry, Fatih University, B.Çekmece, 34500, Istanbul, Turkey

author

Sinan Kazan

• Department of Physics, Gebze Institute of Technology, 41400, Gebze, Kocaeli, Turkey

author

Ramazan Topkaya

• Department of Physics, Gebze Institute of Technology, 41400, Gebze, Kocaeli, Turkey

author

Muhammet Toprak

• Functional Materials Division, Royal Institute of Technology — KTH, SE16440, Stockholm, Sweden

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Identifiers

DOI

10.2478/s11532-010-0037-8