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Journal

2010 | 8 | 3 | 469-485

Article title

Isomers in the chemistry of mercury coordination compounds

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Content

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Languages of publication

EN

Abstracts

EN
The coordination chemistry of mercury is an extremelybroad field, as shown by a survey covering the crystallographic and structural data of over 550 examples. About 12% of those complexes exist as isomers and are summarised and classified in this review. Included are distortion (73%), polymerisation (20.6%), coordination number (3.2%) and ligand (3.2%) isomerism. These are discussed in terms of the coordination around the mercury atoms, and correlations are drawn between donor atoms, bond distances and bond angles. Distortion isomers, differing only by the degree of distortion in the Hg - L and L - Hg - L angles, are the most common. These isomers are discussed and compared with those found in the chemistry of zinc and cadmium. [...]

Publisher

Journal

Year

Volume

8

Issue

3

Pages

469-485

Physical description

Dates

published
1 - 6 - 2010
online
25 - 4 - 2010

Contributors

author
  • Department of Chemical Theory of Drugs, Faculty of Pharmacy, Comenius University, 832 32, Bratislava, Slovak Republik

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-010-0031-1
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