Catalytic activity of thiourea and its selected derivatives on electroreduction of In(III) in chlorates(VII)

• Authors: Agnieszka Nosal-Wiercińska
• Languages of publication: EN

Abstracts

EN

It was found that thiourea, N-methylthiourea, N,N′-dimethylthiourea and N-allylthiourea accelerate the electroreduction process of In(III) ions in chlorates(VII). These substances are adsorbed on mercury from chlorates(VII). The relative surface excesses of thiourea and its derivatives increase with the increase of their concentrations and electrode charge. After adding thiourea, N-methylthiourea, N,N′-dimethylthiourea and N-allylthiourea to the solution an acceleration of the electroreduction process of In(III) ions occurs. This process depends on two factors: the adsorption of an accelerating substance on mercury and on the formation of complexes between a depolarizer and an accelerating substance on the electrode surface. The equilibrium of this complexing reaction determines the magnitude of the catalytic effect. [...]

Keywords

EN

Electroreduction of In(III) ions; Thiourea; N-methylthiourea; N,N′-dimethylthiourea; N-allylthiourea

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 1
• Pages: 1-11

Dates

published

1 - 2 - 2010

online

16 - 2 - 2010

Contributors

author

Agnieszka Nosal-Wiercińska

• Faculty of Chemistry, Maria Curie-Skłodowska Univeristy, 20-031, Lublin, Poland

References

• [1] M.T. Ludwik, Indium (Indium. Corp. of America, New York, 1959)
• [2] J.C. Lin, H.C. Shih, J. Electrochem. Soc. 134, 817 (1987) http://dx.doi.org/10.1149/1.2100578[Crossref]
• [3] M.A. Filyand, E.J. Semenova, Handbook of the Rare Elements (MacDonald, London, 1969)
• [4] J.H. de Bussy, T.J.W. van Thoor (Eds.), Metals and Ores (Longman, London, 1970) vol. 3
• [5] J. Strang, Dental materials 3, 26 (1998)
• [6] Y. Shigesato, S. Takaki, T. Haranoh, J. Appl. Phys. 71, 3356 (1992) http://dx.doi.org/10.1063/1.350931[Crossref]
• [7] J.I. Jeong, J.H. Moon, J.H. Hong, J.S. Kang, Y.P. Lee, Appl. Phys. Lett. 64, 1215 (1994) http://dx.doi.org/10.1063/1.110893[Crossref]
• [8] A. Manisingh, C.V.R. Vasant Kumar, J. Phys. D 22, 455 (1989) http://dx.doi.org/10.1088/0022-3727/22/3/013[Crossref]
• [9] S. Omanovic, M. Metikos-Hukovic, Thin Solid Films 458, 52 (2004) http://dx.doi.org/10.1016/j.tsf.2003.11.271[Crossref]
• [10] K. Nishiyama, H. Ishida, I. Taniguchi, J. Electroanal. Chem. 373, 255 (1994) http://dx.doi.org/10.1016/0022-0728(94)03528-8[Crossref]
• [11] Z. Salamon, G. Tollin, Photochem. Photobiol. 58, 730 (1993) http://dx.doi.org/10.1111/j.1751-1097.1993.tb04960.x[Crossref]
• [12] M. Tominaga, T. Kumagai, S. Takita, I. Taniguchi, Chem. Lett. 10, 1771 (1993) http://dx.doi.org/10.1246/cl.1993.1771[Crossref]
• [13] I. Taniguchi, Y. Mie, K. Nishiyama, V. Brabec, O. Novakova, S. Neya, N. Funasaki, J. Electroanal. Chem. 420, 5 (1997) http://dx.doi.org/10.1016/S0022-0728(96)01022-4[Crossref]
• [14] A.I. Molodov, V.V. Losev, Elektrokhimiya 1,1253 651 (1965)
• [15] J.G. Lawson, D.A. Aikens, J. Electroanal. Chem. 15, 193 (1967) http://dx.doi.org/10.1016/0022-0728(67)85023-X[Crossref]
• [16] R.D. Armstrong, A.B. Suttie, H.R Thirsk, Electrochem. Acta 13, 1 (1968) http://dx.doi.org/10.1016/0013-4686(68)80001-5[Crossref]
• [17] J.I. Turyan, N.K. Strizhow, Elektrokhimiya 11, 458 (1975)
• [18] G. Biedermann, T. Wallin, Acta Chem. Scand. 14, 594 (1960). http://dx.doi.org/10.3891/acta.chem.scand.14-0594[Crossref]
• [19] F.J.C. Rossotti, H. Rossotti, Acta Chem. Scand. 10, 779 (1956) http://dx.doi.org/10.3891/acta.chem.scand.10-0779[Crossref]
• [20] A. Aziz, J.S. Lyle, J. Inorg. Nucl. Chem. 31, 2431 (1969) http://dx.doi.org/10.1016/0022-1902(69)80575-0[Crossref]
• [21] P. Hemmes, L.D. Rich, D.L. Cole, E.M. Eyring, J. Phys. Chem. 74, 2859 (1970) http://dx.doi.org/10.1021/j100709a001[Crossref]
• [22] T.H. Cannon, R.E. Richards, Trans. Faraday Soc. 62, 1378 (1966) http://dx.doi.org/10.1039/tf9666201378[Crossref]
• [23] A. Fratiello, R.E. Lee, V.M. Nishida, R.E. Schuster, J. Phys. 48, 3705 (1968)
• [24] J. Celeda, D.G. Tuck, J. Inorg. Nucl. Chem. 36, 373 (1974) http://dx.doi.org/10.1016/0022-1902(74)80026-6[Crossref]
• [25] M. Maeda, H. Ohtaki, Bull Chem. Soc. Jpn. 50, 1893 (1977) http://dx.doi.org/10.1246/bcsj.50.1893[Crossref]
• [26] M. Eigen, Ber. Bunsenges. Phys. Chem. 67, 753 (1963) [Crossref]
• [27] M. Eigen, Pure Appl. Chem. 6, 97 (1963) http://dx.doi.org/10.1351/pac196306010097[Crossref]
• [28] E.M. Eyring, J.D. Owen, J. Phys. Chem. 74, 1825 (1970) http://dx.doi.org/10.1021/j100704a001[Crossref]
• [29] M. ZeliĆ, M. Mlakar, M. Branica, Anal. Chim. Acta. 289, 299 (1994) http://dx.doi.org/10.1016/0003-2670(94)90005-U[Crossref]
• [30] M.C. Montemayor, E. Fatas, Electrochim. Acta 33, 655 (1988) http://dx.doi.org/10.1016/0013-4686(88)80064-1[Crossref]
• [31] R.R. Nazmutdinov, M.S. Shapnik, O.I. Malyucheva, Elektrokhimiya 29, 331 (1993)
• [32] K. Sykut, G. Dalmata, B. Nowicka, J. Saba, J. Electroanal. Chem. 90, 299 (1978) http://dx.doi.org/10.1016/S0022-0728(78)80065-5[Crossref]
• [33] A. Nosal-Wiercińska, Z. Fekner, G. Dalmata, J. Electroanal. Chem. 584, 192 (2005) http://dx.doi.org/10.1016/j.jelechem.2005.01.044[Crossref]
• [34] A. Nosal-Wiercińska, G. Dalmata, Electrochim. Acta 51, 6179 (2006) http://dx.doi.org/10.1016/j.electacta.2006.01.062[Crossref]
• [35] G. Dalmata, A. Nosal-Wiercińska, Croat. Chem. Acta 81, 529 (2008)
• [36] J. Koryta, J. Dvorak, V. Bohackova, Elektrochemia (PWN, Warszawa, 1980) (In Polish)
• [37] R. Parsons, R. Payne, Z. Phys. Chem. N. F. 98, 9 (1975)
• [38] D.C. Grahame, R.P. Larsen, M.A. Poth, J. Am. Chem. Soc. 71, 2978 (1949) http://dx.doi.org/10.1021/ja01177a010[Crossref]
• [39] D.C. Grahame, E.M. Coffin, J.J. Commings, M.A. Poth, J. Am. Chem. Soc. 74, 1207 (1952) http://dx.doi.org/10.1021/ja01125a021[Crossref]
• [40] D.J. Schiffrin, J. Electroanal. Chem. 23, 168 (1969) http://dx.doi.org/10.1016/S0022-0728(69)80203-2[Crossref]
• [41] R. Parsons, Trans. Faraday Soc. 51, 1518 (1955) http://dx.doi.org/10.1039/tf9555101518[Crossref]
• [42] R. Parsons, Proc. Roy. Soc. A 261, 79 (1961) http://dx.doi.org/10.1098/rspa.1961.0062[Crossref]
• [43] W.F. Schapink, M. Qudeman, K.W. Leu, J.N. Helle, Trans. Faraday Soc. Ser. A 56, 415 (1960) http://dx.doi.org/10.1039/tf9605600415[Crossref]
• [44] R.R. Nazmutdinov, T.T. Zinkicheva, G.A. Tsirlina, Z.V. Kuz’minova, Electrochim. Acta 50, 4888 (2005) http://dx.doi.org/10.1016/j.electacta.2005.02.091[Crossref]
• [45] A. Nosal-Wiercińska, G. Dalmata, Electroanalysis 14, 1275 (2002) http://dx.doi.org/10.1002/1521-4109(200210)14:18<1275::AID-ELAN1275>3.0.CO;2-P[Crossref]
• [46] A. Nosal-Wiercińska, G. Dalmata, Polish J. Chem. 82, 1473 (2008).
• [47] Southampton Electrochemistry Group, Instrumental Methods in Electrochemistry (The Ellis Horwood Ltd, Chichester, 1990) 190
• [48] R.S. Nicholson, J. Shain, Anal. Chem. 36, 706 (1964) http://dx.doi.org/10.1021/ac60210a007[Crossref]
• [49] R.S. Nicholson, Anal. Chem. 37, 1351 (1965) http://dx.doi.org/10.1021/ac60230a016[Crossref]
• [50] A. Barański, S. Fitak, Z. Galus, J. Electroanal. Chem. 60, 175 (1975) http://dx.doi.org/10.1016/S0022-0728(75)80329-9[Crossref]
• [51] D.C. Grahame, J. Am. Chem. Soc. 80, 4261 (1958) http://dx.doi.org/10.1021/ja01549a022[Crossref]
• [52] Z. Galus, The Theoretical Basics of Chemical Electroanalysis (PWN, Warsaw, 1977) (in Polish)
• [53] J.E.B. Randles, Trans Faraday Soc. 44, 327 (1948) http://dx.doi.org/10.1039/tf9484400327[Crossref]
• [54] A. Ševčik, Coll. Czechoslov. Chem. Commun. 13, 349 (1948) [Crossref]
• [55] J.E.B. Randles, In: P. Zumana (Ed.), Progress in Polarography (Interscience Publ., New York, 1962) 1, 123
• [56] Z. Galus, Electroanalytical Methods of Determination of Physicochemical Constants (PWN, Warsaw, 1979) (in Polish)
• [57] H. Matsuda, Y. Ayabe, Z. Elektrochem. 59, 494 (1955)
• [58] O.A. Petrii, R.R. Nazmutdinov, M.D. Bronshtein, G.A. Tsirlina, Electrochim. Acta 52, 3493 (2007). http://dx.doi.org/10.1016/j.electacta.2006.10.014[Crossref]
• [59] D.S. Turnham, J. Electroanal. Chem. 10, 19 (1965) http://dx.doi.org/10.1016/0022-0728(65)85011-2[Crossref]
• [60] R. Tamamushi, K. Ishibashi, N. Tanaka, Z. Phys. Chem. N. F. 35, 209 (1962)
• [61] G. Dalmata, Electroanalysis 17, 789 (2005) http://dx.doi.org/10.1002/elan.200403154[Crossref]

Identifiers

DOI

10.2478/s11532-009-0109-9