Synthesis of MSn(OH)6 (where M = Mg, Ca, Zn, Mn, or Cu) materials at room temperature

• Authors: Jonathan Kramer , Brandon Kelly , Venkatesan Manivannan
• Languages of publication: EN

Abstracts

EN

Applying a metathesis approach (MCl2·xH2O+Na2SnO3·xH2O→MSn(OH)6+NaCl+xH2O), Schoenfliesite-type materials with general formula MSn(OH)6 (where M=Ca, Cu, Mg, Mn or Zn) were synthesized at room-temperature. The high lattice-energy of the by-product alkali halide NaCl drives the reaction in the forward direction leading to the formation of the desired materials. The materials synthesized were characterized by powder X-ray diffraction (XRD) and scanning electron microscopy (SEM) to elucidate structural and micro structural features. [...]

Keywords

EN

Metathesis Reactions; Perovskites; Powder technology; X-ray diffraction; Ceramics

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 1
• Pages: 65-69

Dates

published

1 - 2 - 2010

online

16 - 2 - 2010

Contributors

author

Jonathan Kramer

• Department of Mechanical Engineering, Colorado State University, Fort Collins, CO, 80523, USA

author

Brandon Kelly

• Department of Mechanical Engineering, Colorado State University, Fort Collins, CO, 80523, USA

author

Venkatesan Manivannan

• Department of Mechanical Engineering, Colorado State University, Fort Collins, CO, 80523, USA

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Identifiers

DOI

10.2478/s11532-009-0094-z