Atom transfer radical polymerization in aqueous dispersed media

• Authors: Ke Min , Krzysztof Matyjaszewski
• Languages of publication: EN

Abstracts

EN

During the last decade, atom transfer radical polymerization (ATRP) received significant attention due to its exceptional capability of synthesizing polymers with pre-determined molecular weight, well-defined molecular architectures and various functionalities. It is economically and environmentally attractive to adopt ATRP to aqueous dispersed media, although the process is challenging. This review summarizes recent developments of conducting ATRP in aqueous dispersed media. The issues related to retaining “controlled/living” character as well as colloidal stability during the polymerization have to be considered. Better understanding the ATRP mechanism and development of new initiation techniques, such as activators generated by electron transfer (AGET) significantly facilitated ATRP in aqueous systems. This review covers the most important progress of ATRP in dispersed media from 1998 to 2009, including miniemulsion, microemulsion, emulsion, suspension and dispersed polymerization. [...]

Keywords

EN

ATRP; Controlled radical polymerization; Dispersed media; Emulsion

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2009
• Volume: 7
• Issue: 4
• Pages: 657-674

Dates

published

1 - 12 - 2009

online

6 - 10 - 2009

Contributors

author

Ke Min

• Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA, 15213, USA

author

Krzysztof Matyjaszewski

• Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA, 15213, USA

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Identifiers

DOI

10.2478/s11532-009-0092-1