Solid phase selective separation and green preconcentration of Cu, Zn, Pb and Cd in drinking water by using novel functionalized resin

• Authors: Nagwa Burham , Sami Azeem , Mohamed El-Shahat
• Languages of publication: EN

Abstracts

EN

A new solid - phase extraction sorbent was developed based on stepwise anchoring of two ligand molecules for the determination of copper, zinc, lead and cadmium in drinking water by flame AAS. Amberlite XAD-2 functionalized with 4′-(2-hydroxyphenylazo)-3′-methyl-1′-phenyl-2′-pyrazolin-5′-one (HPAPyr) was utilized for preconcentration/separation of these elements. The sorbent was prepared by two successive azo coupling reactions. First, 2-aminophenol was anchored to the amino groups in the resin resulted from nitration followed by reduction. Then, the resulted 2-aminophenol functionalized resin was further diazotized and coupled to the pyrazolone compound and the final product HPAPyr-XAD-2 was characterized by IR and elemental analysis. The optimum pH range for sorption, shaking time, exchange capacity, sample flow rate, preconcentration factor and interference from co-existing ions were investigated. All metal ions were quantitatively desorbed from the resin by 4.5 mol L−1 nitric acid solution. The sorbent provides limit of detection within the range 0.9–3.3 µg L−1 and concentration factor up to 250. The procedure was validated by analysis of certified material NIST-SRM 1577b. Application to drinking water showed satisfactory results with relative standard deviation RSD ≤ 8.5%. [...]

Keywords

EN

Pyrazolone; Amberlite XAD-2; Heavy metals; Preconcentration

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2009
• Volume: 7
• Issue: 4
• Pages: 945-954

Dates

published

1 - 12 - 2009

online

6 - 10 - 2009

Contributors

author

Nagwa Burham

• Chemistry Department, Faculty of Science, Fayoum University, 11371, Fayoum City, Egypt

author

Sami Azeem

• Chemistry Department, Faculty of Science, Fayoum University, 11371, Fayoum City, Egypt

author

Mohamed El-Shahat

• Chemistry Department, Faculty of Science, Ain Shams University, 11341, Cairo, Egypt

References

• [1] A.A. Ensafi, A.R. Ghaderi, J. Hazard. Mater. 148, 319 (2007) http://dx.doi.org/10.1016/j.jhazmat.2007.02.037[Crossref]
• [2] I. Narin, Y. Surme, E. Bercin, M. Soylak, J. Hazard. Mater. 145, 113 (2007) http://dx.doi.org/10.1016/j.jhazmat.2006.11.001[Crossref]
• [3] Y. Cai, G.B. Jiang, J.F. Liu, Analyst 126, 1678 (2001) http://dx.doi.org/10.1039/b105866p[Crossref]
• [4] R.G. Wuilloud, G.M. Wuilloud, J.C.A. de Wuilloud, R.A. Olsina, L.D. Martinez, At. Spectrosc 23, 44 (2002)
• [5] S. Samal, S. Acharya, R.K. Dey, A.R. Ray, Talanta 57, 1075 (2002) http://dx.doi.org/10.1016/S0039-9140(02)00144-3[Crossref]
• [6] N. Burham, S.M. Abdel-Azeem, M.F. El-Shahat, Anal. Chim. Acta 579, 193 (2006) http://dx.doi.org/10.1016/j.aca.2006.07.032[Crossref]
• [7] W.X. Ma, F. Liu, K.A. Li, W. Chen, S.Y. Tong, Anal. Chim. Acta 416, 191 (2000) http://dx.doi.org/10.1016/S0003-2670(00)00886-2[Crossref]
• [8] M. Tuzen, M. Soylak, Anal. Chim. Acta 504, 325 (2004) http://dx.doi.org/10.1016/j.aca.2003.10.043[Crossref]
• [9] W.N.L. dos Santos, C.M.C. Santos, S.L.C. Ferreira, Microchem. J. 75, 211 (2003) http://dx.doi.org/10.1016/S0026-265X(03)00099-7[Crossref]
• [10] N. Burham, S.M. Abdel-Azeem, F. El-Shahat, Inter. J. Envir. Anal. Chem. 88, 775 (2008) http://dx.doi.org/10.1080/03067310801958692[Crossref]
• [11] N. Burham, Cent. Eur. J. Chem. 6, 641 (2008) http://dx.doi.org/10.2478/s11532-008-0065-9[Crossref]
• [12] N. Burham, S.M. Abdel-Azeem, F. El-Shahat, Cent. Eur. J. Chem. 7, 576 (2009) http://dx.doi.org/10.2478/s11532-009-0051-x[Crossref]
• [13] J. Fan, C. Wu, Y. Wei, C. Peng, P. Peng, J. Hazard. Mater. 145, 323 (2007) http://dx.doi.org/10.1016/j.jhazmat.2006.11.025[Crossref]
• [14] M. Dogru, R. Gul-Guven, S. Erdogan, J. Hazard. Mater. 149, 166 (2007) http://dx.doi.org/10.1016/j.jhazmat.2007.03.066[Crossref]
• [15] U. Divrikli, A. Akdogan, M. Soylak, L. Elci, J. Hazard. Mater. 149, 331 (2007) http://dx.doi.org/10.1016/j.jhazmat.2007.03.084[Crossref]
• [16] A. Sabarudin, O. Noguchi, M. Oshima, K. Higuchi, S. Motomizu, Microchim. Acta 159, 41 (2007) http://dx.doi.org/10.1007/s00604-007-0734-y[Crossref]
• [17] S. Cadore, R.D. Goi, N. Baccan, J. Brazil Chem. Soc. 16, 957 (2005)
• [18] V.A. Lemos, P.X. Baliza, J.S. Santos, L.S. Nunes, A.A. Jesus, M.E. Rocha, Talanta 66, 174 (2005) http://dx.doi.org/10.1016/j.talanta.2004.11.004[Crossref]
• [19] I. Narin, M. Tuzen, M. Soylak, Talanta 63, 411 (2004) http://dx.doi.org/10.1016/j.talanta.2003.11.005[Crossref]
• [20] S.D. Cekic, H. Filik, R. Apak, Anal. Chim. Acta 505, 15 (2004) http://dx.doi.org/10.1016/S0003-2670(03)00211-3[Crossref]
• [21] L.S.G. Teixeira, M.A. Bezerra, V.A. Lemos, H.C. dos Santos, D.S. de Jesus, A.C.S. Costa, Separ. Sci. Technol. 40, 2555 (2005) http://dx.doi.org/10.1080/01496390500267707[Crossref]
• [22] V.A. Lemos, M.A. Bezerra, F.A.C. Amorim, J. Hazard. Mater. 157, 613 (2008) http://dx.doi.org/10.1016/j.jhazmat.2008.01.027[Crossref]
• [23] V.K. Jain, S.S. Sait, P. Shrivastav, Y.K. Agrawal, Talanta 45, 39 (1997) http://dx.doi.org/10.1016/S0039-9140(97)00141-0[Crossref]
• [24] R. Saxena, A.K. Singh, D.P.S. Rathore, Analyst 120, 403 (1995) http://dx.doi.org/10.1039/an9952000403[Crossref]
• [25] R. Saxena, A.K. Singh, S.S. Sambi, Anal. Chim. Acta 295, 199 (1994) http://dx.doi.org/10.1016/0003-2670(94)80351-X[Crossref]
• [26] B. Wen, X.Q. Shan, R.X. Liu, H.X. Tang, Fresenius J. Anal. Chem. 363, 251 (1999) http://dx.doi.org/10.1007/s002160051183[Crossref]
• [27] M. Kumar, D.P.S. Rathore, A.K. Singh, Talanta 51, 1187 (2000) http://dx.doi.org/10.1016/S0039-9140(00)00295-2[Crossref]
• [28] Y. Higashi, D. Jitsuiki, K. Chayama, M. Yoshizumi, Recent Patents on Cardiovascular Drug Discovery 1, 85 (2006) http://dx.doi.org/10.2174/157489006775244191[Crossref]
• [29] A. Tong, Y. Akama, Analyst 115, 947 (1990) http://dx.doi.org/10.1039/an9901500947[Crossref]
• [30] P. Liang, J. Li, X. Yang, Microchimica Acta 152, 47 (2005) http://dx.doi.org/10.1007/s00604-005-0415-7[Crossref]
• [31] S. Zhimei, L. Pei, D. Qiong, C. Jing, Analytical Sciences 22, 911 (2006) http://dx.doi.org/10.2116/analsci.22.911[Crossref]
• [32] V.A. Lemos, S.L.C. Ferreira, Anal Chim Acta 441, 281 (2001) http://dx.doi.org/10.1016/S0003-2670(01)01125-4[Crossref]
• [33] V.K. Jain, A. Handa, S.S. Sait, P. Shrivastav, Y.K. Agarwal, Anal. Chim. Acta 429, 237 (2001) http://dx.doi.org/10.1016/S0003-2670(00)01299-X[Crossref]
• [34] S. Baytak, E. Kendüzler, A.R. Türker, N. Gök, J. Hazard. Mater. 153, 975 (2008) http://dx.doi.org/10.1016/j.jhazmat.2007.09.049[Crossref]
• [35] S. Baytak, E. Kendüzler, A.R. Türker, Sep. Sci. Technol. 41, 3449 (2006) http://dx.doi.org/10.1080/01496390600915098[Crossref]
• [36] M. Soylak, M. Tüzen, D. Mendil, I. Türkekul, Talanta 70, 1129 (2006) http://dx.doi.org/10.1016/j.talanta.2006.02.027[Crossref]
• [37] Y.W. Liu, X.J. Chang, Y. Guo, S.M. Meng, J. Hazard. Mater. 135, 389 (2006) http://dx.doi.org/10.1016/j.jhazmat.2005.11.078[Crossref]

Identifiers

DOI

10.2478/s11532-009-0089-9