Full-text resources of PSJD and other databases are now available in the new Library of Science.
Visit https://bibliotekanauki.pl

PL EN


Preferences help
enabled [disable] Abstract
Number of results

Journal

2009 | 7 | 4 | 675-682

Article title

Miniaturization of flow-through generation cells for electrochemical hydride generation in AAS

Content

Title variants

Languages of publication

EN

Abstracts

EN
The construction and optimization of five new types of miniaturized flow-through electrolytic cells with lead cathode and platinum anode for electrochemical hydride generation in atomic absorption spectrometry (HG-QFAAS) were achieved during this research study. The ion-exchange membrane was not part of these cells and only one carrying electrolyte for both electrode chambers was used. Hydride generation efficiency achieved was either comparable or higher than the one recorded for the classic thin-layer generation cell. The inner volume of the cathode chamber was reduced to a quarter of the classic thin-layer flow-through cell. Compared to the commonly used thin-layer flow-through cell, higher sensitivity (7.32×103 dm3 µg−1) and better limit of detection (0.32 µg dm−3) were obtained for selenium determination using two of these new generators. [...]

Publisher

Journal

Year

Volume

7

Issue

4

Pages

675-682

Physical description

Dates

published
1 - 12 - 2009
online
6 - 10 - 2009

Contributors

author
  • Faculty of Science, Department of Analytical Chemistry, Charles University in Prague, Prague 2, CZ 128 43, Czech Republic
author
  • Faculty of Science, Department of Analytical Chemistry, Charles University in Prague, Prague 2, CZ 128 43, Czech Republic
  • Faculty of Science, Department of Analytical Chemistry, Charles University in Prague, Prague 2, CZ 128 43, Czech Republic

References

  • [1] J. Dědina, D. Tsalev, Hydride Generation Atomic Absorption Spectrometry (Wiley, Chichester, 1995)
  • [2] Y.H. Lin, X.R. Wang, D.X. Yuan, P.Y. Yang, B.L. Huang, Z.X. Zhuang, J. Anal. Atom. Spectrom. 7, 287 (1992) http://dx.doi.org/10.1039/ja9920700287[Crossref]
  • [3] L. Brockmann, C. Nonn, A. Golloch, J. Anal. Atom. Spectrom. 8, 397 (1993) http://dx.doi.org/10.1039/ja9930800397[Crossref]
  • [4] D.M. Hueber, J.D. Winefordner, Anal. Chim. Acta 316, 129 (1995) http://dx.doi.org/10.1016/0003-2670(95)00364-6[Crossref]
  • [5] J. Šíma, P. Rychlovský, Chem. Listy 92, 676 (1998) (in Czech)
  • [6] W.W. Ding, R.E. Sturgeon, J. Anal. At. Spectrom. 11, 225 (1996) http://dx.doi.org/10.1039/ja9961100225[Crossref]
  • [7] W.W. Ding, R.E. Sturgeon, Spectrochim. Acta, Part B 51, 1325 (1996) http://dx.doi.org/10.1016/0584-8547(96)01514-5[Crossref]
  • [8] E. Denkhaus, A. Golloch, T.U. Kampen, M. Nierfeld, U. Telgheder, Fresenius J. Anal. Chem. 361, 733 (1998) http://dx.doi.org/10.1007/s002160051007[Crossref]
  • [9] C. Schickling, J.F. Yang, J.A.C. Broekaert, J. Anal. At. Spectrom. 11, 739 (1996) http://dx.doi.org/10.1039/ja9961100739[Crossref]
  • [10] L.F. Machado, A.O. Jacintho, A.A. Menegario, E.A. Zagatto, M.F. Gine, J. Anal. At. Spectrom. 13, 1343 (1998) http://dx.doi.org/10.1039/a806383d[Crossref]
  • [11] U. Pyell, A. Dworschak, F. Nitschke, B. Neidhart, Fresenius J. Anal. Chem. 363, 495 (1999) http://dx.doi.org/10.1007/s002160051232[Crossref]
  • [12] J. Šíma, P. Rychlovský, J. Dědina, Spectrochim. Acta, Part B 59, 125 (2004) http://dx.doi.org/10.1016/j.sab.2003.11.005[Crossref]
  • [13] J. Šíma, P. Rychlovský, Spectrochim. Acta, Part B 58, 919 (2003) http://dx.doi.org/10.1016/S0584-8547(03)00035-1[Crossref]
  • [14] V. Červený, P. Rychlovský, J. Netolická, J. Šíma, Spectrochim. Acta, Part B 62, 317 (2007) http://dx.doi.org/10.1016/j.sab.2006.12.009[Crossref]
  • [15] W. Zhang, W. Gan, X. Lin, Anal. Chim. Acta 539, 335 (2005) http://dx.doi.org/10.1016/j.aca.2005.03.050[Crossref]
  • [16] D. Schaumlöffel, B. Neidhart, Fresenius J. Anal. Chem. 354, 866 (1996)
  • [17] D.M. Hueber, J.D. Winefordner, Anal. Chim. Acta 316, 129 (1995) http://dx.doi.org/10.1016/0003-2670(95)00364-6[Crossref]
  • [18] F. Laborda, E. Bolea, J.R. Castillo, J. Anal. At. Spectrom. 15, 103 (2000) http://dx.doi.org/10.1039/a905270d[Crossref]
  • [19] E. Denkhaus, A. Golloch, X.M. Guo, B. Huang, J. Anal. Atom. Spectrom, 16, 870 (2001) http://dx.doi.org/10.1039/b100185j[Crossref]
  • [20] F. Laborda, E. Bolea, J.R. Castillo, Anal. Bioanal. Chem. 388, 743 (2007) http://dx.doi.org/10.1007/s00216-006-1037-6[Crossref]
  • [21] B. Ozmena, F.M. Matysika, N.H. Bings, J.A.C. Broekaert, Spectrochim. Acta, Part B 59, 941 (2004) http://dx.doi.org/10.1016/j.sab.2004.04.006[Crossref]
  • [22] D.L. Tsalev, J. Anal. At. Spectrom. 14, 147 (1999) http://dx.doi.org/10.1039/a807304j[Crossref]
  • [23] V. Červený, P. Rychlovský, In: S. Ružičková (Ed.), XVIIth Slovak Spectroscopic conference, 5–9 Sep. 2004, The High Tatras - Tatranské Zruby, Slovakia (Technical University Košice, Košice, 2004)
  • [24] J. Hraníček, V. Červený, P. Rychlovský, Chem. Listy 102, 200 (2008) (in Czech)
  • [25] L.F. Machado, A.O. Jacintho, M.F. Gine, Química Nova 23, 30 (2000)
  • [26] E. Bolea, F. Laborda, J.R. Castillo, Anal. Sci. 19, 367 (2003) http://dx.doi.org/10.2116/analsci.19.367[Crossref]

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-009-0066-3
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.