Nuclear magnetic resonance spectroscopic studies of the trihexyl (tetradecyl) phosphonium chloride ionic liquid mixtures with water

• Authors: Jerrod Dwan , Dan Durant , Khashayar Ghandi
• Languages of publication: EN

Abstracts

EN

Tetra-alkyl Phosphonium ionic liquids are phosphonium salts with melting points near room temperature. We report the NMR studies of water-trihexyl (tetradecyl) phosphonium chloride ionic liquid mixtures. The proton chemical shifts were used to investigate the intermolecular interactions in mixtures of ionic liquids and water. The OH chemical shifts were found to decrease as the water concentration in the ionic liquid increased, and their rate of change with temperature decreased with water concentration. The CH2 and CH3 chemical shifts were found to move downfield with the increase in temperature, and moved further downfield as water concentration was decreased. The interface of experimental data and the results of quantum calculations suggest a significant binding of phosphonium cations to chloride anion and water molecules. As well, the analysis of the data suggests a possible transformation from cationchloride-water configuration at low water concentrations to cation-water-water at higher water concentrations. [...]

Keywords

EN

Ionic liquids; Intermolecular interactions; NMR

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2008
• Volume: 6
• Issue: 3
• Pages: 347-358

Dates

published

1 - 9 - 2008

online

11 - 8 - 2008

Contributors

author

Jerrod Dwan

• Mount Allison University, Sackville, NB, Canada

author

Dan Durant

• Mount Allison University, Sackville, NB, Canada

author

Khashayar Ghandi

• Mount Allison University, Sackville, NB, Canada

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Identifiers

DOI

10.2478/s11532-008-0034-3