Polyaniline-polypyrrole coating for solid phase microextraction

• Authors: Vida Vickackaite , Vilma Ciuvasovaite
• Languages of publication: EN

Abstracts

EN

A procedure for direct electrochemical deposition of polyaniline-polypyrrole blend coating on the surface of stainless steel wire was suggested. Incorporation of polyaniline and polypyrrole into the blend coating was confirmed by infrared spectroscopy. Key parameters (pyrrole, aniline, dopant and sulphuric acid concentrations and deposition potential) influencing the coating’s mechanical stability and surface homogeneity were optimised and thermostability of the coating was investigated. A possibility to apply the coating as a new fibre for solid phase microextraction was demonstrated. The coating showed better selectivity toward aromatic, hydrophobic compounds. [...]

Keywords

EN

Solid phase microextraction; polyaniline; polypyrrole; gas chromatography

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2007
• Volume: 5
• Issue: 3
• Pages: 727-738

Dates

published

1 - 9 - 2007

online

1 - 9 - 2007

Contributors

author

Vida Vickackaite

• Department of Analytical and Environmental Chemistry, Vilnius University, Naugarduko 24, LT-03225, Vilnius, Lithuania

author

Vilma Ciuvasovaite

• Department of Analytical and Environmental Chemistry, Vilnius University, Naugarduko 24, LT-03225, Vilnius, Lithuania

References

• [1] R. Belardi and J. Pawliszyn: “The application of chemically modified fused silica fibers in the extraction of organics from water matrix samples and their rapid transfer to capillary columns”, Water Pollut. Res. J. Canada, Vol. 24, (1989), pp. 179–185.
• [2] J. Pawliszyn: Solid phase microextraction. Theory and practice., Wiley-VCH, New York, 1997.
• [3] G.A. Mills and V. Walker: “Headspace solid-phase microextraction procedures for gas chromatographic analysis of biological fluids and materials”, J. Chromatogr. A, Vol. 902, (2000), pp. 267–287. http://dx.doi.org/10.1016/S0021-9673(00)00767-6[Crossref]
• [4] Supelco Chromatography. Products for Analysis & Purification (2005–2006), Catalog, Sigma-Aldrich Co. USA, 2005.
• [5] Y. Liu, Y. Shen and M.L. Lee: “Porous layer solid phase microextraction using silica bounded phases”, Anal. Chem., Vol. 69, (1997), pp. 190–195. http://dx.doi.org/10.1021/ac960791g[Crossref]
• [6] Y. Liu and L. Lee: “Solid-phase microextraction of PAHs from aqueous samples using fibers coated with HPLC chemically bounded silica stationary phases”, Anal. Chem., Vol. 69, (1997), pp. 5001–5005. http://dx.doi.org/10.1021/ac970686m[Crossref]
• [7] M. Farajzadeh and N.A. Rahmani: “Alumina-based fiber for solid phase microextraction of alcohols from gaseous samples”, Anal. Sci., Vol. 20, (2004), pp. 1359–1362. http://dx.doi.org/10.2116/analsci.20.1359[Crossref]
• [8] M. Farajzadeh and M. Hatami: “Analysis of n-alkanes at sub microgram per liter level after direct solid phase microextraction from aqueous samples”, Anal. Sci., Vol. 18, (2002), pp. 1221–1225. http://dx.doi.org/10.2116/analsci.18.1221[Crossref]
• [9] D. Panavaite, A. Padarauskas and V. Vickackaite: “Silicone glue coated stainless steel wire for solid phase microextraction”, Anal. Chim. Acta, Vol. 571, (2006), pp. 45–50. http://dx.doi.org/10.1016/j.aca.2006.04.035[Crossref]
• [10] A. Ramanaviciene and A. Ramanavicius: “Application of polypyrrole for the creation of immunosensors”, Crit. Rev. Anal. Chem., Vol. 32, (2002), pp. 245–253. http://dx.doi.org/10.1080/10408340290765542[Crossref]
• [11] R. Rajagopalan and J.O. Iroh: “Electrodeposition of adherent polyanilinepolypyrrole composite coatings on low carbon steel”, J. Adhesion, Vol. 78, (2002), pp. 835–860. http://dx.doi.org/10.1080/00218460214097[Crossref]
• [12] A. Mohammadi, Y. Yamini and N. Alizadeh: “Dodecylsulfate-doped polypyrrole film prepared by electrochemical fiber coating technique for headspace solid-phase microextraction of polycyclic aromatic hydrocarbons”, J. Chromatogr. A, Vol. 1063, (2005), pp. 1–8. http://dx.doi.org/10.1016/j.chroma.2004.11.087[Crossref]
• [13] J. Wu and J. Pawliszyn: “Preparation and applications of polypyrrole films in solidphase microextraction”, J. Chromatogr. A, Vol. 909, (2001), pp. 37–52 http://dx.doi.org/10.1016/S0021-9673(00)01025-6[Crossref]
• [14] J. Wu, X. Yu, H. Lord and J. Pawliszyn: “Solid phase microextraction of inorganic anions based on polypyrrole film”, Analyst, Vol. 125, (2000), pp. 391–394. http://dx.doi.org/10.1039/b000287i[Crossref]
• [15] J. Wu and J. Pawliszyn: “Solid-phase microextraction based on polypyrrole films with different counter ions”, Anal. Chim. Acta, Vol. 520, (2004), pp. 257–264. http://dx.doi.org/10.1016/j.aca.2004.05.019[Crossref]
• [16] Dj. Djozan, M.H. Pouraghi-Azar and S. Bahar: “Modified polypyrrole with tetrasulfonated nickel phthalocyanine as a fiber for solid-phase microextraction. Application to the extraction of BTEX compounds from water samples”, Chromatographia, Vol. 59, (2004), pp. 595–599. http://dx.doi.org/10.1365/s10337-004-0222-z[Crossref]
• [17] J. Wu, W.M. Mullett and J. Pawliszyn: “Electrochemically controlled solid-phase microextraction based on conductive polypyrrole films”, Anal. Chem., Vol. 74, (2002), pp. 4855–4859. http://dx.doi.org/10.1021/ac025595q[Crossref]
• [18] H. Bagheri, A. Mir and E. Babanezhad: “An electropolimerized aniline-based fiber coating for solid phase microextraction of phenols from water”, Anal. Chim. Acta, Vol. 532, (2005), pp. 89–95. http://dx.doi.org/10.1016/j.aca.2004.10.040[Crossref]
• [19] A. Ghassempour, N. Mashkouri Najafi, A. Mehdinia, S. Saeed Hosseiny Davarani, M. Fallahi and M. Nakhshab: “Analysis of anatoxin-a using polyaniline as a sorbent in solid-phase microextraction coupled to gas chromatography-mass spectrometry”, J. Chromatogr. A, Vol. 1078, (2005), pp. 120–127. http://dx.doi.org/10.1016/j.chroma.2005.04.053[Crossref]
• [20] M. Huang, G. Jiang and Y. Cai: “Electrochemical preparation of composite polyaniline coating and its application in the determination of bisphenol A, 4-n-nonylphenol, 4-tert-octylphenol using direct solid phase microextraction coupled with high performance liquid chromatography”, J. Sep. Sci., Vol. 28, (2005), pp. 2218–2224. http://dx.doi.org/10.1002/jssc.200500091[Crossref]
• [21] H. Minjia, T. Chao, Z. Qunfang and J. Guibin: “Preparation of polyaniline coating on a stainless-steel wire using electroplating and its application to the determination of six aromatic amines using headspace solid-phase microextraction”, J. Chromatogr. A, Vol. 1048, (2004), pp. 257–262. http://dx.doi.org/10.1016/j.chroma.2004.07.059[Crossref]
• [22] X. Li, M. Zhong, S. Xu and Ch. Sun: “Determination of phthalates in water samples using polyaniline-based solid-phase microextraction coupled with gas chromatography”, J. Chromatogr A, Vol. 1135, (2006), pp. 101–108. http://dx.doi.org/10.1016/j.chroma.2006.09.051[Crossref]
• [23] J.O. Iroh and R. Rajagopalan: “Electrochemical synthesis of polyaniline-polypyrrole composite coatings on carbon fibres in aqueous toluene sulphonate solution”, Surf. Eng., Vol. 16, (2000), pp. 481–486. http://dx.doi.org/10.1179/026708400101517477[Crossref]
• [24] C. Thiemann and C.M.A. Brett: “Electrosynthesis and properties of conducting polymers derived from aminobenzoic acids and from aminobenzoin acids and aniline”, Synthetic met., Vol. 123, (2001), pp. 1–9. http://dx.doi.org/10.1016/S0379-6779(00)00364-7[Crossref]

Identifiers

DOI

10.2478/s11532-007-0023-y