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Journal

2007 | 5 | 2 | 516-535

Article title

Comparative study of layered tetravalent metal phosphates containing various first-row divalent metals. Synthesis, crystalline structure

Content

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EN

Abstracts

EN
The transition metal forms of α-zirconium-. titanium-, and hafnium phosphates were prepared by ion exchange method. Their structure was investigated by X-ray powder diffraction (XRPD) method. It was found that the transition metal containing phosphates have the same layered structure as the pristine tetravalent metal phosphates, except for the increase of interlayer distance from 7.6 Å to ∼9.5 Å. As a result of the incorporation of transition metals in the layers, the c-axis is increased from ∼15 Å to ∼20 Å (in the case of titanium phosphate to ∼25 Å). All other parameters (a, b and β °) are practically unchanged. [...]

Keywords

Publisher

Journal

Year

Volume

5

Issue

2

Pages

516-535

Physical description

Dates

published
1 - 6 - 2007
online
2 - 2 - 2007

Contributors

  • Institute of Isotopes, Hungarian Academy of Sciences, H-1525, Budapest, Hungary
  • Institute of Isotopes, Hungarian Academy of Sciences, H-1525, Budapest, Hungary
  • Institute of Isotopes, Hungarian Academy of Sciences, H-1525, Budapest, Hungary
author
  • Research Group of Nuclear Methods in Structural Chemistry, Department of Nuclear Chemistry, HAS, Eötvös Lóránd University, H-1518, Budapest, Hungary

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-007-0003-2
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