Influence of complexation on the composition of equilibrium phases in the system of Ce2(SO4)3-La2(SO4)3

• Authors: Maria Milanova , Dimitar Todorovsky , Christo Balarew , Natalia Minkova , Katya Ivanova
• Languages of publication: EN

Abstracts

EN

The cocrystallization of Ce2(SO4)3 and La2(SO4)3 is studied in aqueous and H2SO4 (150 g/dm3) solutions at 25 °C and 64 °C. The effect of the formation of inner sphere sulfate complexes of the type LnSO 4+ in determining the composition of the equilibrium phases is revealed. [...]

Keywords

EN

Ce-sulfates; complexes; La-sulfates; solid solutions; solubility

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2007
• Volume: 5
• Issue: 1
• Pages: 13-19

Dates

published

1 - 3 - 2007

online

1 - 3 - 2007

Contributors

author

Maria Milanova

• Faculty of Chemistry, University of Sofia, Sofia, 1164, Bulgaria

author

Dimitar Todorovsky

• Faculty of Chemistry, University of Sofia, Sofia, 1164, Bulgaria

author

Christo Balarew

• Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Sofia, 1113, Bulgaria

author

Natalia Minkova

• Faculty of Chemistry, University of Sofia, Sofia, 1164, Bulgaria

author

Katya Ivanova

• Faculty of Chemistry, University of Sofia, Sofia, 1164, Bulgaria

References

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Identifiers

DOI

10.2478/s11532-006-0060-y