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Journal

2006 | 4 | 3 | 403-427

Article title

Solvent reduced wittig olefination reactions with halo containing conjugated phosphoranes

Content

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EN

Abstracts

EN
The Wittig reaction of carbaldehydes with alkoxycarbonylhalomethylidenetriphenylphosphoranes can be performed with ease in solventless systems. The analogous reaction of carbaldehydes with acylhalomethylidenetriphenylphosphoranes requires a small amount of solvent, such as chloroform, in order for the reaction to proceed. The products of the reaction are versatile precursors for further transformations, such as the Suzuki-Miyaura cross-coupling reaction.

Publisher

Journal

Year

Volume

4

Issue

3

Pages

403-427

Physical description

Dates

published
1 - 9 - 2006
online
1 - 9 - 2006

Contributors

  • Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan
author
  • Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan
author
  • Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan
  • Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan

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bwmeta1.element.-psjd-doi-10_2478_s11532-006-0024-2
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