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Journal

2006 | 4 | 2 | 317-328

Article title

Synthesis, characterization and optical properties of silver and gold nanowires embedded in mesoporous MCM-41

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Languages of publication

EN

Abstracts

EN
Uniform nanowires of silver and gold inside the channels of MCM-41 were prepared by controlled reduction of their respective metal salts with sodium borohydride (NaBH4). Presence of nanowires of silver and gold in MCM-41 were confirmed by high angle X-ray diffraction (XRD) data (peaks between 2ϑ = 30 − 60°) and transmission electron microscopy (TEM) confirmed the diameter of the nanowires. Diameter of nanowires is found to be ∼ 2.8 nm which is coincident with channel diameter of MCM-41. Optical properties of these heterostructured materials Ag-MCM-41 and Au-MCM-41 reveals the presence of surface plasmon absorption peaks of silver and gold respectively, and the shift in the absorption bands are associated to agglomeration of clusters inside the channels. Room temperature photoluminescence spectra exhibits interesting optical properties as observed for direct band gap semiconductors. Non-linear optical properties (NLO) corresponding to second harmonic generation (SHG) values were also recorded for self supported films of these heterostructured materials. Enhanced optical non-linearity was found to be arising from a corresponding increase of local field near the surface plasmon resonance. Further enhancement in SHG was found with poling due to an induction of orientation order.

Keywords

Publisher

Journal

Year

Volume

4

Issue

2

Pages

317-328

Physical description

Dates

published
1 - 6 - 2006
online
1 - 6 - 2006

Contributors

  • Center for Materials for Electronics Technology, Panchwati, Pune, 411008, India
  • National Chemical Laboratory, Pune, 411008, India
author
  • Department of Physics, University of Pune, Ganesh Khind, Pune, 411007, India
author
  • Department of Physics, University of Pune, Ganesh Khind, Pune, 411007, India
  • National Chemical Laboratory, Pune, 411008, India

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-006-0006-4
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