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Journal

2006 | 4 | 2 | 299-316

Article title

Formation and multinuclear magnetic resonance investigation of silylammonium tetracarbonylcobaltate contact ion pairs

Content

Title variants

Languages of publication

EN

Abstracts

EN
Silylcobalt tetracarbonyls were reacted with various amines (B) in non-polar solvents to form silylammonium tetracarbonylcobaltate contact ion pairs formulated as [BSiR3+, −Co(CO)4]. The compounds were characterized by IR and multinuclear magnetic resonance spectroscopy both in solution and in solid state. Their properties are analogous to the known ion pairs [BH+, −Co(CO)4] and to amine adducts of halosilanes as well.

Publisher

Journal

Year

Volume

4

Issue

2

Pages

299-316

Physical description

Dates

published
1 - 6 - 2006
online
1 - 6 - 2006

Contributors

author
  • Research Group for Petrochemistry, Hungarian Academy of Sciences, H-8200, Veszprém, Hungary
  • Department of Silicate and Materials Engineering, NMR laboratory, University of Veszprém, H-8200, Veszprém, Hungary

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-006-0005-5
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