Leaching of vanadium(V) from the mixture after potassium metavanadate synthesis based on KCl and spent vanadium catalyst

• Authors: Urszula Kiełkowska , Katarzyna Białowicz , Sebastian Drużyński
• Languages of publication: EN

Abstracts

EN

The results of the leaching of vanadium(V) from the mixture after potassium metavanadate synthesis from KCl and spent vanadium catalyst in the presence of steam were presented. Spent vanadium catalyst was obtained from the waste storage of a chemical plant producing sulfuric acid(VI) by the contact method. The reaction mixture was leached using different solutions: 1 M Na2CO3, 20% CO(NH2)2, 15% NaOH, 15% KOH, 2 M H2SO4. The effect of time and temperature was studied. The results showed that for reaction mixture leached for 4 h at 303 K in the presence of 15% sodium hydroxide solution at a liquid:solid ratio of 10:1, the extent of leaching of vanadium(V) was 95.43%.

Keywords

EN

KVO3 synthesis; spent vanadium catalyst; leaching; recovery; iron; vanadium(V)

• Publisher: De Gruyter Open
• Journal: Polish Journal of Chemical Technology
• Year: 2013
• Volume: 15
• Issue: 4
• Pages: 33-35

Dates

published

1 - 12 - 2013

online

31 - 12 - 2013

Contributors

author

Urszula Kiełkowska

• Nicolaus Copernicus University, Faculty of Chemistry, 7 Gagarin Street, 87-100 Toruń, Poland

author

Katarzyna Białowicz

• Nicolaus Copernicus University, Faculty of Chemistry, 7 Gagarin Street, 87-100 Toruń, Poland

author

Sebastian Drużyński

• Nicolaus Copernicus University, Faculty of Chemistry, 7 Gagarin Street, 87-100 Toruń, Poland

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Identifiers

DOI

10.2478/pjct-2013-0064