Translocation of Cations During Sorption of Copper in the System Solution - Algae (Spirogyra sp.)/Translokacja Kationów Podczas Procesu Sorpcji Miedzi W Układzie Roztwór - Glony (Spirogyra Sp.)

• Authors: Małgorzata Rajfur , Andrzej Kłos , Jan Kříž
• Languages of publication: EN

Abstracts

EN

Kinetics of the sorption of copper cations in Spirogyra sp. algae was analysed, together with the accompanying processes of hydrogen cations sorption and releasing to the solution the cations bonded in the algae: Na+, Mg2+, K+ and Ca2+. It was established that, in a static system, at the fixed proportion of algae mass to the solution volume, these processes occur simultaneously, however presumably the quantity of the released salts influences the parameters of heterophase equilibrium of ion exchange. In the experiment conditions, the quantity of the released cations was nearly 10 times larger than the quantity of the sorbed cations. The equilibrium parameters, determined from the model of pseudo second order reaction, were compared with the parameters obtained after 30 min of the process duration, ie at relatively stable indications of measuring equipment. On the example of the sorbed copper, the difference is approximately 8%. It was confirmed that the solution conductivity is a good parameter for the estimation of the state close to equilibrium.

PL

Zbadano kinetykę procesu sorpcji kationów miedzi w glonach Spirogyra sp. oraz towarzyszące mu procesy sorpcji kationów wodorowych i procesy uwalniania do roztworu kationów związanych w glonach: Na+, Mg2+, K+ i Ca2+. Stwierdzono, że w układzie statycznym, przy stałym stosunku masy glonów do objętości roztworu, procesy te zachodzą równocześnie, przy czym należy przypuszczać, że ilość uwalnianych soli ma wpływ na parametry heterofazowej równowagi wymiany jonowej. W warunkach prowadzenia eksperymentu ilość uwolnionych kationów była blisko 10-krotnie większa niż ilość kationów sorbowanych. Porównano parametry równowagi wyznaczone z modelu reakcji pseudo-drugiego rzędu z parametrami uzyskanymi po 30 min trwania procesu, to jest przy względnie stałych wskazaniach przyrządów pomiarowych. Różnica na przykładzie sorbowanej miedzi wynosi ok. 8%. Stwierdzono, że dobrym parametrem do szacowania stanu bliskiemu stanowi równowagi jest konduktywność roztworu.

Keywords

EN

algae; copper cations; biosorption; ion exchange equilibrium

PL

glony; kationy miedzi; biosorpcja; równowaga wymiany jonowej

• Publisher: De Gruyter Open
• Journal: Ecological Chemistry and Engineering S
• Year: 2014
• Volume: 21
• Issue: 3
• Pages: 425-433

Dates

published

1 - 10 - 2014

online

10 - 10 - 2014

Contributors

author

Małgorzata Rajfur

• Chair of Biotechnology and Molecular Biology, Opole University, ul. kard. B. Kominka 6, 45-032 Opole, Poland, phone [phone], fax [phone]

author

Andrzej Kłos

• Chair of Biotechnology and Molecular Biology, Opole University, ul. kard. B. Kominka 6, 45-032 Opole, Poland, phone [phone], fax [phone]

author

Jan Kříž

• Faculty of Science, University of Hradec Kralove, Rokitanskeho 62, 500 03 Hradec Kralove, Czech Republic

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Identifiers

DOI

10.2478/eces-2014-0031