New transformation of cycloalkanone acetals by peracids α,ω-dicarboxylic acids synthesis

• Authors: Alexander Terent'ev , Sergey Chodykin
• Languages of publication: EN

Abstracts

EN

A new process of oxidation of cycloalkanone acetals under the action of in situ generated performic acid has been found. The main products of the reaction are α, ω-dicarboxylic acids obtained with the yield up to 77% depending on the size of acetals ring. The process has been explored and optimized on the example of the dodecanedioic acid synthesis (a valuable industrial product).

Keywords

EN

Cycloalkanone acetals; hydrogen peroxide; dodecanedioic acid; dicarboxylic acid; performic acid; enol-ether; oxidation; Baeyer-Villiger rearrangement

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2005
• Volume: 3
• Issue: 3
• Pages: 417-431

Dates

published

1 - 9 - 2005

online

1 - 9 - 2005

Contributors

author

Alexander Terent'ev

• N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Leninsky Prospect 47, Moscow, Russia

author

Sergey Chodykin

• N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Leninsky Prospect 47, Moscow, Russia

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Identifiers

DOI

10.2478/BF02479272