X-Ray and EPR study on copper (II) complexes with an enamine ligand

• Authors: Anife Ahmedova , Maria Vaz , Samuele Ciattini , Georgi Gochev , Andrea Caneschi , Mariana Mitewa
• Languages of publication: EN

Abstracts

EN

The enamine (HEAID) obtained from aniline and 2-acetyl-1,3-indandione (2AID) behaves as a bidentate ligand in coordination with copper (II) ion. Two types of crystals, apparently different in shape, were isolated and studied by single-crystal X-ray diffraction. The X-ray data for the brown rhombic crystals of compound 1 shows a mononuclear complex of Cu(II) coordinated with two EAID-anions, Cu(EAID)2. The X-ray data for the green crystals of compound 2 shows a dinuclear Cu(II) complex with two OH− groups acting as bridging ligands, [Cu2(μ-OH)2(EAID)2]. In both cases the ligand coordinates after deprotonation of the amine group.

Keywords

EN

X-ray structure; EPR; Cu(II) complexes; enamine of 2-Acetyl-1,3-indandione

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2005
• Volume: 3
• Issue: 1
• Pages: 146-156

Dates

published

1 - 3 - 2005

online

1 - 3 - 2005

Contributors

author

Anife Ahmedova

• Department of Chemistry, University of Sofia, 1, J. Bourchier av., 1126, Sofia, Bulgaria

author

Maria Vaz

author

Samuele Ciattini

• Dipartimento di Chimica, Università degli Studi di Firenze, Via della Lastruccia 3, 1-50019, Sesto Fiorentino (FI), Italy

author

Georgi Gochev

• Department of Chemistry, University of Sofia, 1, J. Bourchier av., 1126, Sofia, Bulgaria

author

Andrea Caneschi

author

Mariana Mitewa

• Department of Chemistry, University of Sofia, 1, J. Bourchier av., 1126, Sofia, Bulgaria

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Identifiers

DOI

10.2478/BF02476245