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Number of results

Journal

2005 | 3 | 3 | 395-408

Article title

Study of solid-solution hardening in binary aluminium-based alloys

Content

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Languages of publication

EN

Abstracts

EN
Solid-solution formation in binary aluminium-based alloys is due essentially to the combined effects of the size and valence of solvent and solute atoms, as expected by the four Hume-Rothery rules. The lattice parameter of aluminium in the solid solution of the sputtered Al−Fe films is [Al-a (Å)=4.052−6.6×10−3Y]. The increasing and decreasing evolution of the lattice parameter of copper [Cu-a (Å)=3.612+1.8×10−3Z] and aluminium [Al-a (Å)=4.048−1.6×10−3X] in the sputtered Al-1.8 to 92.5 at. % Cu films is a result of the difference in size between the aluminium and copper atoms. The low solubility of copper in aluminium (<1.8 at % Cu) is due to the valences of solvent and solute atoms in contrast with other sputtered films prepared under similar conditions, such as Al−Mg (20 at. % Mg), Al−Ti (27 at. % Ti), Al−Cr (5at. % Cr) and Al−Fe (5.5 at. % Fe) where the solubility is due to the difference in size.

Publisher

Journal

Year

Volume

3

Issue

3

Pages

395-408

Physical description

Dates

published
1 - 9 - 2005
online
1 - 9 - 2005

Contributors

  • Département de Physique, Faculté des Sciences, Université Badji-Mokhtar, BP 12 Annaba, 23000, Algérie
  • Département de Physique, Faculté des Sciences, Université Badji-Mokhtar, BP 12 Annaba, 23000, Algérie

References

  • [1] M. Draissia: Structure et physico-chimie des dépôts métastables aluminium-cuivre élaborés par pulvérisation cathodique magnétron, Thesis (PhD) Université Badji-Mokhtar Annaba (Algérie), 2004.
  • [2] M. Draissia, H. Boudemagh and M.Y. Debili: “Structure and Hardness of the Sputered Al−Cu Thin Films System”, Physica Scripta, Vol. 69, (2004), pp. 348–350. http://dx.doi.org/10.1238/Physica.Regular.069a00348[Crossref]
  • [3] M. Draissia and M.Y. Debili: “Atomic size effects on the hardness of r.f. Sputtered Al−Cu(Rich) thin films”, Journal of Crystal Growth, Vol. 270, (2004), pp. 250–254. http://dx.doi.org/10.1016/j.jcrysgro.2004.06.003[Crossref]
  • [4] R.D. Arnell and R.I. Bates: “The deposition of highly supersaturated metastable aluminium-magnesium by unbalanced magnetron sputtering from composite target”, Vacuum, Vol. 43, (1992), pp. 105–109. http://dx.doi.org/10.1016/0042-207X(92)90193-Z[Crossref]
  • [5] F. Sanchette, Tran Huu Loï and C. Frantz: “Structure-properties relationship of metastable Al−Cr and Al−Ti alloys deposited by r.f. magnetron sputtering: role of nitrogen”, Surf. Coat. Technol., Vol. 74–75, (1995), pp. 903–909. http://dx.doi.org/10.1016/0257-8972(94)08210-3[Crossref]
  • [6] F. Sanchette, Tran Huu Loï, A. Billard and C. Frantz: “Deposition of metastable aluminium-chromium alloys by r.f. magnetron sputtering from mixed-powder targets”, Surf. Coat. Technol., Vol. 57, (1993), pp. 179–182. http://dx.doi.org/10.1016/0257-8972(93)90037-O[Crossref]
  • [7] M.Y. Debili, Tran Huu Loï and C. Frantz: “Caractérisation chimique et structurale de dépôts métastables aluminium-fer obtenus par pulvérisation cathodique magnétron”, La revue de Métallurgie-CIT/Science et Génie des Matériaux, Vol. 12, (1998), pp. 1501–1509.
  • [8] Unpublished results: M. Draissia, H. Boudemagh and M.Y. Debili: “Observation d’une démixtion dans des films minces nanostructurés Al-66.64 at.%Cu obtenus par dépôt physique en phase vapeur (PVD)”, presented at the conference: The 3rd Int. Cong. on Mat. Sci. & Eng., Jijel (Algérie) 25–27 May 2004.
  • [9] Unpublished results: M. Draissia, H. Boudemagh and M.Y. Debili: “Unexpected phase separation in magnetron sputter-deposited Al−Cu thin films system”, presented at the conference: IX mes Journées Maghrébines des Sciences des Matériaux JMSM, Oran (Algérie) 8–10 May 2004.
  • [10] Unpublished results: M. Draissia and M.Y. Debili: “Corrosion behaviour of nanostructured aluminium-based alloys”, presented at the conference: 7 mes Journées Francophones des Jeunes Physico-Chimistes, Monastir (Tunisie) 19–21 March 2004.
  • [11] Unpublished results: M. Draissia, M.Y. Debili and J.P. Millet: “Structural and chemical properties of sputtered Al−Cu deposits”, presented at the conference: Eurocorr 2004, Nice (France) 12–16 September 2004.
  • [12] J. Axon and W. Hume-Rothery: Proc. Roy. Soc. A, Vol. 193, (1948), p. 1.
  • [13] C. Ellwood and J.M. Silcock: J. Ins. Met., Vol. 74, (1948), p. 457.
  • [14] A.J. Bradley and H.J. Goldschmidt: J. Inst. Met., Vol. 65, (1939), p. 389.
  • [15] I. Obinata and J. Wassermann: Naturwiss, Vol. 21, (1933), p. 382. http://dx.doi.org/10.1007/BF01451794[Crossref]
  • [16] H. Stirling and G.V. Raynor: Private communication and J. Inst. Met, Vol. 84, (1955), p. 57.
  • [17] V. Fournée, I. Mazin, D.A. Papaconstantapoulos and E. Belin-Ferré: “Electronic structure calculations of Al−Cu alloys: comparison with experimental results on Hume-Rothery pahases”, Philosophical Magazine B, Vol. 79(2), (1999), pp. 205–221. http://dx.doi.org/10.1080/014186399257320[Crossref]
  • [18] R.W.K. Honeycombe: The Plastic Deformation of Metals, 2nd ed., Arnold, UK, 1984.
  • [19] M. Draissia, N. Boukhris and M.Y. Debili: “Thermomechanical behavior of rapidly solidified Fe-25Cr-20Ni”, Materials Science Forum, Vol. 467–470, (2004), pp. 247–250. http://dx.doi.org/10.4028/www.scientific.net/MSF.467-470.247[Crossref]
  • [20] H. Wang, M.J. Zaluzec and J.M. Rigsbee: “Microstructure and Mechanical Properties of Sputter-Deposited Cu1−x Tax Alloys”, Metall. Trans. A, Vol. 28, (1997), pp. 917–925.

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_BF02475646
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