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2015 | 17 | 2 | 51-56

Article title

The use of the steric effect of the carrier molecule in the polymer inclusion membranes for the separation of cobalt(II), nickel(II), copper(II), and zinc(II) ions

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EN

Abstracts

EN
In this study, palladium-modified nickel foam substrate was applied to examine ethanol oxidation reaction (EOR) in 0.1 The transport of cobalt(II), nickel(II), copper(II), and zinc(II) ions from chloride solutions across polymer inclusion membranes (PIMs), which 1-heptylimidazole (1̲) or 1-heptyl-2-methylimidazole (2̲) or 1-heptyl-4-methylimidazole (3̲) as the ion carrier was reported. The steric effect for carriers 2̲and 3̲decreases the transport of all ions except Cu(II). The initial fl uxes of metal ions transport across PIMs with the 1̲- 2̲decrease in the sequence: Cu(II) > Zn(II) > Co(II) > Ni(II), whereas for 3 they were Cu(II) > Zn(II) > Ni(II) > Co(II). The highest recovery values were obtained for Cu(II), this being 99 and 85% for carrier 1̲and 2̲, respectively. In both membranes the degree of deposition of the Zn(II) ions was comparable. Zn(II), Co(II) and Cd(II) ions, which form complexes with coordination numbers 4 and 6, are more easily recovered with the use of carriers 2̲and 3̲. Ni(II) ions, which form complexes with coordination number 6 only, practically remain in the feeding phase. PIMs with alkylimidazoles were characterized by non-contact atomic force microscopy.

Publisher

Year

Volume

17

Issue

2

Pages

51-56

Physical description

Dates

published
1 - 6 - 2015
online
9 - 6 - 2015

Contributors

  • University of Science and Technology, Department of Inorganic Chemistry, ul. Seminaryjna 3, 85-326 Bydgoszcz, Poland
  • Czestochowa University of Technology, Department General Building Engineering and Building Physics, Faculty of Civil Engineering, ul. Akademicka 3, 42-200 Czestochowa, Poland

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_1515_pjct-2015-0029
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