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Journal

2015 | 60 | 1 | 127-131

Article title

Determination of hyperfine fields and atomic ordering in NiMnFeGe exhibiting martensitic transformation

Content

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Languages of publication

EN

Abstracts

EN
The hyperfine fields and atomic ordering in Ni1−xFexMnGe (x = 0.1, 0.2, 0.3) alloys were investigated using X-ray diffraction and Mössbauer spectroscopy at room temperature. The X-ray diffraction measurements show that the samples with x = 0.2, 0.3 crystallized in the hexagonal Ni2In-type of structure, whereas in the sample with x = 0.1, the coexistence of two phases, Ni2In- and orthorhombic TiNiSi-type of structures, were found. The Mössbauer spectra measured with x = 0.2, 0.3 show three doublets with different values of isomer shift (IS) and quadrupole splitting (QS) related to three different local surroundings of Fe atoms in the hexagonal Ni2In-type structure. It was shown that Fe atoms in the hexagonal Ni2In-type structure of as-cast Ni1−xFexMnGe alloys are preferentially located in Ni sites and small amount of Fe is located in Mn and probably in Ge sites. The spectrum for x = 0.1 shows the doublets in the central part of spectrum and a broad sextet. The doublets originate from the Fe atoms in the paramagnetic state of hexagonal Ni2In-type structure, whereas the sextet results from the Fe atoms in orthorhombic TiNiSi-type structure.

Publisher

Journal

Year

Volume

60

Issue

1

Pages

127-131

Physical description

Dates

published
1 - 3 - 2015
online
12 - 3 - 2015
accepted
17 - 11 - 2014
received
18 - 6 - 2014

Contributors

  • Faculty of Physics, University of Bialystok, 1L K. Ciołkowskiego Str., 15-245 Białystok, Poland, Tel.: +48 85 738 8167, Fax: +48 85 745 7223
  • Faculty of Physics, University of Bialystok, 1L K. Ciołkowskiego Str., 15-245 Białystok, Poland, Tel.: +48 85 738 8167, Fax: +48 85 745 7223
  • Faculty of Physics, University of Bialystok, 1L K. Ciołkowskiego Str., 15-245 Białystok, Poland, Tel.: +48 85 738 8167, Fax: +48 85 745 7223
  • Faculty of Physics, University of Bialystok, 1L K. Ciołkowskiego Str., 15-245 Białystok, Poland and ALBA Synchrotron Light Source, Crta. BP 1413, Km. 3.3, 08290 Cerdanyola del Vallès, Barcelona, Spain
  • Institute of Chemistry, University of Bialystok, 1 Hurtowa Str., 15-399 Białystok, Poland

References

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  • 2. Liu, E., Wang, W., Feng, L., Zhu, W., Li, G., Chen, J., Zhang, H., Wu, G., Jiang, C., Xu, H., & de Boer, F. (2012). Stable magnetostructural coupling with tunable magnetoresponsive effects in hexagonal ferromagnets. Nat. Commun., 3, 873-p10. DOI: 10.1038/ncomms1868.[WoS][Crossref]
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  • 5. Zhang, C. L., Wang, H. D., Cao, Q. Q., Han, Z. D., Xuan, H. C., & Du, Y. W. (2008). Magnetostructural phase transition and magnetocaloric effect in off-stoichiometric Mn1.9-xNixGe alloys. Appl. Phys. Lett., 93, 122505-3p. DOI:10.1063/1.2990649.[Crossref][WoS]
  • 6. Bażela, W., Szytuła, A., Todorović, J., Tomkowicz, Z., & Zięba, A. (1976). Crystal and magnetic structure of NiMnGe. Phys. Status Solidi A-Appl. Mat., 38, 721–729. DOI: 10.1002/pssa.2210380235.[Crossref]
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  • 8. Satuła, D., Dobrzyński, L., Waliszewski, J., Szymański, K., Rećko, K., Malinowski, A., Brückel, Th., Schärpf, O., & Blinowski, K. (1997). Structural and magnetic properties of Fe-Cr-Al alloys with DO3-type of structure. J. Magn. Magn. Mater., 169, 240–252. DOI: 10.1016/S0304-8853(96)00758-5.[Crossref]
  • 9. Satuła, D., Szymański, K., Dobrzyński, L., Waliszewski, J., & Malinowski, A. (1995). Local environments effects and site preference in Fe3-xCrxAl alloys. J. Magn. Magn. Mater., 140/144, 61–62. DOI: 10.1016/0304-8853(94)01049-8.[Crossref]
  • 10. Szymański, K., Biernacka, M., Dobrzyński, L., Perzyńska, K., Rećko, K., Satuła, D., Waliszewski, J., & Zaleski, P. (2000). Mössbauer and magnetic studies of Fe3-xCoxAl. J. Magn. Magn. Mater., 210, 150–162. DOI: 10.1016/S0304-8853(99)00644-7.[Crossref]
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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_1515_nuka-2015-0026
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