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2014 | 27 | 4 | 213-216

Article title

Kinetics of the decomposition and the estimation of the stability of 10% aqueous and non-aqueous hydrogen peroxide solutions

Content

Title variants

Languages of publication

EN

Abstracts

EN
In this study, the stability of 10% hydrogen peroxide aqueous and non-aqueous solutions with the addition of 6% (w/w) of urea was evaluated. The solutions were stored at 20°C, 30°C and 40°C, and the decomposition of hydrogen peroxide proceeded according to first-order kinetics. With the addition of the urea in the solutions, the decomposition rate constant increased and the activation energy decreased. The temperature of storage also affected the decomposition of substance, however, 10% hydrogen peroxide solutions prepared in PEG-300, and stabilized with the addition of 6% (w/w) of urea had the best constancy.

Publisher

Year

Volume

27

Issue

4

Pages

213-216

Physical description

Dates

published
1 - 12 - 2014
received
25 - 10 - 2014
online
3 - 3 - 2015
accepted
8 - 12 - 2014

Contributors

author
  • Chair and Department of Applied Pharmacy, Faculty of Pharmacy, Medical University of Lublin, 1 Chodzki, 20-093 Lublin, Poland
  • Chair and Department of Applied Pharmacy, Faculty of Pharmacy, Medical University of Lublin, 1 Chodzki, 20-093 Lublin, Poland
  • Chair and Department of Applied Pharmacy, Faculty of Pharmacy, Medical University of Lublin, 1 Chodzki, 20-093 Lublin, Poland
  • Chair and Department of Applied Pharmacy, Faculty of Pharmacy, Medical University of Lublin, 1 Chodzki, 20-093 Lublin, Poland
  • Chair and Department of Applied Pharmacy, Faculty of Pharmacy, Medical University of Lublin, 1 Chodzki, 20-093 Lublin, Poland
  • Chair and Department of Synthesis and Chemical Technology of Pharmaceutical Substances with Computer Modeling Unit., Faculty of Pharmacy with Division of Medical Analytics, Medical University of Lublin, 4a Chodzki, 20-093 Lublin, Poland
author
  • Chair and Department of Applied Pharmacy, Faculty of Pharmacy, Medical University of Lublin, 1 Chodzki, 20-093 Lublin, Poland

References

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  • 9. Login R.B. et al.: Stabilization of disinfectant urea-hydrogen peroxide complexes with PVP. US 5,183,901 (Cl. 548-543; C01B15/01), 02 Feb 1993, Appl. 825,359, 24 Jan 1992.
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  • 14. Zuń M., et al.: Influence of concentration of the urea on the hydrogen peroxide content in 3% aqueous and non-aqueous solutions stored at different temperatures. Ann UMCS Sect DDD. 2, 47-55, 2011.

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_1515_cipms-2015-0017
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