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Franck-Condon Effects in Resonance Raman Spectra of TCNQ^{-} and C_{10}H^{+8} Radicals. A Search for Dushinsky Rotation of Totally Symmetric Modes

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Zborowski K., Pawlikowski M.

Acta Physica Polonica A

1995

vol. 88

issue 3

435-444

The resonance Raman spectra of tetracyanoquinodimethane anion (TCNQ^{-}) and naphthalene cation (C_{10}H^{+8}) are analyzed in terms of theoretical model based on the Franck-Condon effects. The model includes also the effect of rotation of totally symmetric normal coordinates upon electronic excitation to the resonant state (Dushinsky effects). It is shown that such a simple model accounts correctly for the available resonance Raman spectra for TCNQ^{-} and C_{10}H^{+8} radicals. The possible model refinements such as vibronic coupling effects are also briefly discussed.

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1 Acta Physica Polonica A

1 1995

1 Pawlikowski M.

1 Zborowski K.

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Franck-Condon Effects in Resonance Raman Spectra of TCNQ^{-} and C_{10}H^{+8} Radicals. A Search for Dushinsky Rotation of Totally Symmetric Modes