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Adsorption and Thermodynamic Studies for Corrosion Inhibition of API 5L X-52 Steel in 2 M HCl Solution by Moxifloxacin

100%
Ikpi M. E., Abeng F. E., Obono O. E.
World News of Natural Sciences
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2017
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vol. 9
52-61
EN
The inhibition of API 5L X-52 steel corrosion in an acidic medium by moxifloxacin at 303 K, 313 K and 323 K was monitored by potentiodynamic polarization measurement. The concentration of acid medium was maintained throughout the experiment. The inhibition efficiency was found to increased with increase in concentration of moxifloxacin and temperature. Activation energy, adsorption and thermodynamic parameters were evaluated from the study temperature. Herein, moxifloxacin brought about a decrease in activation energy Ea that reflects chemisorption. The adsorption of the moxifloxacin on the steel surface was found to obeyed Langmuir adsorption isotherm ΔGads values, indicating strong and spontaneous adsorption of the moxifloxacin on the surface of API 5L X-52 steel.
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Thermodynamic analysis of medium pressure reciprocating natural gas expansion engines

88%
Farzaneh-Gord M., Izadi S., Pishbin S. I., Sheikhani H., Deymi-Dashtebayaz M.
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EN
Natural gas pressure has to be reduced from medium pressure of 1.724 MPa (250 psia) to lower pressure of 0.414 MPa (60 psia) at Town Border pressure reduction Station (TBS). Currently, the pressure reduction is carried out by throttling valves while considerable amount of pressure energy is wasted. One of the equipment which could be used to recover this waste energy is the reciprocating expansion engine. The purpose of this research is to simulate one-sided reciprocating expansion engine thermodynamically for TBS pressure range. The simulation is based on first law of thermodynamics, conversation of mass and ideal gas assumptions. The model could predict in-cylinder pressure and in-cylinder temperature at various crank angles. In addition, the effects of the engine geometrical characteristics, such as intake and exhaust port area and ports timing on the Indicated work per cycle output are investigated.
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