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Modification of PET surface properties using extremely non-equilibrium oxygen plasma

100%
Junkar I., Modic M., Mozeti M.
Open Chemistry
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2015
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vol. 13
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issue 1
EN
Polyethylene terephthalate (PET) foils have been exposed to oxygen plasma and its afterglow in order to reveal compositional and structural modifications of the surface layer. Oxygen plasma was created by electrode-less RF discharge in a glass chamber so the O-atom density was close to 1022 m-3 although the density of charged particles was only about 1 × 1016 m-3. Long-living reactive particles created in plasma were leaked into the afterglow chamber using a two-stage rotary pump of pumping speed 4.4 × 10-3 m3 s-1. The density of O-atoms in the afterglow as measured with a catalytic probe was 3 × 1021 m-3, while the density of reactive oxygen molecules was estimated theoretically. The functionalization was accomplished even after a brief exposure to either plasma or afterglow since all samples were saturated with oxygen-rich functional groups as revealed by XPS. The water contact angle measurements, however, showed that only plasma treatment allowed for super-hydrophilicity, explained by rich surface morphology as detected by AFM. The differences in morphological properties between plasma and afterglow treated samples were explained by different interaction mechanisms between low and high energy particles impinging the polymer surface.
2
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EFFECT OF AMMONIUM SULFATE ON THE SULFIDATION FLOTATION OF MALACHITE

100%
Liu C., Feng Q., Zhang G.
Archives of Mining Sciences
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2018
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vol. 63
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issue 1
3
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Characterization of TiO2surface following the modification with silane coupling agents

86%
Jesionowski T., Siwińska-Stefańska K., Krysztafkiewicz A., Sójka-Ledakowicz J., Koprowska J., Pęczkowska B.
Polish Journal of Chemical Technology
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2007
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vol. 9
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issue 4
72-76
EN
Studies were conducted on the modification of titanium white surface using selected silane coupling agents. The effect of the concentration of the organic coupling agents was examined (0.5; 1 or 3 weight parts per 100 weight parts of TYTANPOL R-003, TYTANPOL R-211 or TYTANPOL R-213 preparation of titanium white). The dispersive properties were determined by an estimation of the particle size distribution curves and of the polydispersity index. Moreover, microscopic observations were conducted permitting to evaluate the surface morphology of the modified TiO2 particles. The profiles of sedimentation in water were also determined for the titanium whites and the BET specific surface areas were determined. Selected samples of the modified and unmodified titanium whites were subjected to elemental analysis.
4
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The morphological and dispersive characterization of commercial titanium dioxides

86%
Jesionowski T., Siwińska-Stefańska K., Krysztafkiewicz A., Sójka-Ledakowicz J., Koprowska J., Lewartowska J.
Polish Journal of Chemical Technology
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2007
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vol. 9
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issue 4
28-35
EN
The physicochemical and dispersive characterizations were conducted on the selected commercial titanium dioxides produced by, Z. Ch. POLICE, S. A. The dispersive properties were defined in detail by an analysis of particle size distribution and polydispersity index. Moreover, the microscope studies were executed to evaluate the surface morphology of the studied TiO2 forms. The profiles of titanium dioxides sedimentation in water were determined and the specific surface areas were defined by the BET method.
5
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EFFECTS OF DIFFERENT NITRIDING METHODS ON NITRIDED LAYER STRUCTURE AND MORPHOLOGY

86%
Frączek T., Jasiński J. J., Sitarz M., Kurpaska Ł., Lubas M.
Archives of Metallurgy and Materials
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2018
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vol. 63
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issue 1
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