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Novel side reactions accompanying activation and aminolysis of N-benzoyl-2-alkylserines.

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Kamiński Z. J., Woszczyna A., Kolesińska B., Redliński A.
|
2001
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vol. 48
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issue 4
1175-1178
EN
2-Phenyl-4-alkyl-4-hydroxymethyl-1,3-oxazolones (2a-d) have been identified as side products accompanying activation of N-benzoyl-2-alkylserines (1a-d). Oxazolones 2a-d in the presence of amine rearrange subsequently to corresponding 4-alkyl-2-phenyl-4,5-dihydro-1,3-oxazole-5 carboxylic acids (4a-d) at a 20-68% yield.
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