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Infinite octamolybdate chains cross-linked by paramagnetic iron (II) centers

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Patrut A., Nicoara A., Margineanu D., Koop M., Kögerler P., Bögge H., Schmidtmann M.
Open Chemistry
|
2004
|
vol. 2
|
issue 2
323-333
EN
The paper presents a new polymeric polyoxomolybdate cluster with infinite octamolybdate chains cross-linked by iron (II) centers. The layer-type substance contains sodium cations sandwiched between the [Fe(H2O)4Mo8O27]∞ layers. The structure was determined by single crystal X-ray diffraction analysis. Magnetic properties, due to the presence of paramagnetic iron (II) centers, are presented and discussed.
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