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Modification of current-voltage characteristics of planar organic systems by nm-thick copper phthalocyanine or perylene dye interlayer

100%
Signerski R., Jarosz G.
Open Physics
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2013
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vol. 11
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issue 2
264-268
EN
The effect of a nm-thick interlayer of copper phthalocyanine (CuPc) or perylene dye (MePTCDI) on currentvoltage characteristics of planar organic systems is discussed in this work. The MePTCDI layer in the ITO/MePTCDI/CuPc/Au system strongly reduces reverse dark current by blocking injection of holes from ITOinto CuPc leading to high values of rectification ratio. The CuPc interlayer in the ITO/CuPc/MePTCDI/Ag system causes a strong reduction in electron injection from ITOand reverses a forward polarity. Modification of current-voltage characteristics of illuminated systems with an interlayer of MePTCDI or CuPc is associated with a strong photovoltaic effect. This results from efficient excition dissociation at the CuPc/MePTCDI interface. Saturation current, determined by this process of charge carrier photogeneration, can be observed at particular voltage polarity.
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Preliminary studies of phthalocyanine sensitizers incorporated into human leukemia cells from two cell-lines.

88%
Wiktorowicz K., Cofta J., Dudkowiak A., Waszkowiak A., Frąckowiak D.
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vol. 51
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issue 3
703-710
EN
Three phthalocyanine dyes-sensitizers were incorporated into two types of human T leukemia cells from two cell-lines: CCRF and MOLT 4. The efficiency of the dye incorporation into cells and photochemical properties of stained cells were investigated using fluorescence spectroscopy. The dyes exhibited different properties in each of the two cell-lines. Small differences in cell membrane properties have a strong influence on the efficiency of dye incorporation and on the course of photodynamic reaction. It is suggested that, for a given patient, an optimal dye-sensitizer should be established before photodynamic treatment.
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