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1
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Inclusion-dependent mechanism of modification of cyclodextrins with heterocycles

100%
Musiol R., Girek T.
Open Chemistry
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2005
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vol. 3
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issue 4
742-746
EN
Mono(6-deoxy-dimethylpyridinium)-β-cyclodextrins have been synthesized in reaction of mono (p-toluenesulfonyl) derivative of β cyclodextrin with the appropriate lutidine under microwave irradiation and conventional conditions. The results indicate that the mechanism consists of inclusion complex formation.
2
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Microwave Assisted Fast Synthesis of CuO Nanoflakes: Catalytic Application in the Synthesis of 1,4-Dihydropyridine

100%
Bajaj S., Tekade P., Lakhotiya G., Borkar P.
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EN
CuO nanoflakes were successfully synthesized by microwave irradiation, using copper(II) sulphate and sodium hydroxide (NaOH) as the starting materials and ethanol as the solvent. The CuO nanoflakes were characterized by using techniques such as X-ray powder diffraction, field emission scanning electron microscopy, and UV-visible absorption spectroscopy, Fourier transform infra-red spectroscopy. The synthesized CuO nanoflakes were found to have morphology like nanoflakes with narrow size distribution and high purity. Moreover, the synthesized CuO nanoflakes were used as an efficient catalyst for synthesis of a series of dihydropyridine derivatives. Optimization studies with different catalysts and solvents reveal that CuO nanoparticle in the water/ethanol mixture is efficient catalyst/solvent system for the synthesis of dihydropyridine derivative.
3
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Reactions of substituted furo[3,2-b]pyrrole-5-carboxhydrazides and their biological activity

88%
Ga, Zbojek D., Lácová M., Král'ová K., Gatial A., Horváth B., Krutošíková A.
Open Chemistry
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2005
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vol. 3
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issue 4
622-646
EN
The reactions of substituted furo[3,2-b]pyrrole-5-carboxhydrazides 1 with 5-arylfuran-2-carboxaldehydes 2, 4,5-disubstituted furan-2-carboxaldehydes 3 and thiophene-2-carboxaldehyde 4 has been studied. The advantage of microwave irradiation on some of these reactions was reflected in the reduced reaction time and increased yields. Reactions of 1 with 4-substituted 1,3-oxazol-5(4H)-ones 11 led to diacylhydrazines 13 or to imidazole derivatives 14 depending on the temperature. 1,2,4-Triazole-3-thione 17 was synthesized by two-step reaction of 1 with phenylisothiocyanate and subsequent base-catalyzed cyclization of thiosemicarbazide 16. The effects of hydrazones 5–10 on inhibition of photosynthetic electron transport in spinach chloroplasts and chlorophyll content in the antialgal suspensions of Chlorella vulgaris were investigated.
4
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Switchable multicomponent heterocyclizations for diversity oriented synthesis

75%
Chebanov V. A., Desenko S. M.
Diversity Oriented Synthesis
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2012
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vol. 1
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issue 1
EN
The present comprehensive review1 contains the analysis of literature data concerning switchable multicomponent heterocyclizations and demonstrates the application of these types of reactions to solve the matters of Diversity Oriented Synthesis.
5
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Influence of Microwave Pre-Treatment on the Digestion and Higienisation of Waste Activated Sludge/Wpływ Dezintegracji Mikrofalowej Na Proces Fermentacji Oraz Higienizacji Nadmiernych Osadów Ściekowych

63%
Bohdziewicz J., Kuglarz M., Grűbel K.
Ecological Chemistry and Engineering S
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2014
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vol. 21
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issue 3
447-464
EN
The article presents the results of determining the most appropriate conditions of microwave sludge pre-treatment (500-1200 W), prior to its anaerobic digestion in a continuous mode. The assessment of the pre-treatment conditions (microwave power, sludge temperature after pre-treatment) was based on: the release of organic (COD, protein) and inorganic (NH4+, PO43-) substances into liquid, the quantity of methane produced, sludge higienisation and the susceptibility of the pre-treated sludge to dewatering. The power of the microwaves applied did not play significant role on the pre-treatment effectiveness. Taking into account the fact that sludge pre-treatment by microwave irradiation requires the delivery of energy, the pre-treatment by microwaves of higher power (1200 W) and resulting in sludge temperature of 70°C was recommended for further experiments. Sludge pre-treatment by means of microwave irradiation as a pre-treatment step influenced the effectiveness of the subsequent anaerobic digestion, conducted in continuous conditions, in a positive way. The largest amount of biogas was obtained for HRT in the range of 15-20 days. As compared to the sludge which did not undergo pre-treatment, daily biogas production and biogas yield increased by 18-41% and 13-35% respectively. The combination of microwave pre-treatment and mesophilic anaerobic digestion ensured the elimination of pathogens (Salmonella spp., Escherichia coli).
PL
Celem badań przedstawionych w artykule było wyznaczenie najkorzystniejszych warunków prowadzenia procesu dezintegracji mikrofalowej (500-1200 W) osadów ściekowych przed ich przeróbką w warunkach beztlenowych (warunki ciągłe). Oceny efektywności procesu mikrofalowej dezintegracji osadów (moc mikrofal, temperatura) dokonano, kierując się stężeniem związków organicznych (ChZT, białka rozpuszczalne) uwolnionych do cieczy nadosadowych, wskaźnikami jakościowymi produkowanego biogazu, stopniem higienizacji oraz podatnością osadów przefermentowanych na odwadnianie. Na podstawie przeprowadzonych badań ustalono, iż moc zastosowanego promieniowania mikrofalowego nie wpłynęła w znaczący sposób na efektywność procesu dezintegracji. Biorąc pod uwagę efektywność oraz zapotrzebowanie energetyczne, ustalono, iż najkorzystniejsze warunki prowadzenia procesu dezintegracji mikrofalowej zapewnia zastosowanie mikrofal o mocy 1200 W oraz temperatury osadów wynoszącej 70°C. Dezintegracja mikrofalowa osadów ściekowych za pomocą promieniowania mikrofalowego wpłynęła korzystnie na efektywność procesu fermentacji metanowej prowadzonego w warunkach ciągłych. Najkorzystniejsze wskaźniki produkowanego biogazu uzyskano dla HRT wynoszącego 15-20 dni. W tych warunkach dobowa i jednostkowa produkcja biogazu wzrosły odpowiednio o 18-41% oraz 13-35%. Zastosowanie dezintegracji mikrofalowej przed procesem mezofilowej fermentacji zapewniło całkowitą eliminację mikroorganizmów patogennych (Salmonella spp., Escherichia coli).
6
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2-[3-(Trifluoromethyl)phenyl]furo[3,2-b]pyrroles: synthesis and reactions

63%
Gajdoš P., Pavlíková S., Bureš F., Krutošíková A.
Open Chemistry
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2005
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vol. 3
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issue 2
311-325
EN
The synthesis and reactions of methyl 2-[3-(trifluoromethyl)phenyl]-4H-furo[3,2-b]pyrrole-5-carboxylate (1a) are described. Upon reaction with methyl iodide, benzyl chloride, or acetic anhydride, this compound gave N-substituted products 1b-d. By hydrolysis of compounds 1a-c, the corresponding acids 2a-c were formed, or by reaction with hydrazine-hydrate, the corresponding carbohydrazides 3a-c were formed. By heating 2-[3-(trifluoromethyl)phenly]-4H-furo[3,2-b]pyrrole-5-carboxylic acid (2a) in acetic anhydride, 4-acetyl-2-[3-(trifluoromethyl)phenyl]furo[3,2-b]pyrrole (4) was formed. By hydrolysis of 4, 2-[3-(trifluoromethyl)phenyl]-4H-furo[3,2-b]pyrrole (5a) was formed, and reactions with methyl iodide or benzyl chloride gave N-substituted products 5b-c. The reaction of 4 with dimethyl butynedioate gave substituted benzo[b]furan 6. Compound 3a reacted with triethyl orthoesters giving 7a-c, which afforded with phosphorus (V) sulphide the corresponding thiones 8a-c. The thiones 8a-c reacted with hydrazine hydrate to form hydrazine derivatives 9a-c. The reaction of triethyl orthoformiate with compounds 9a-c led to furo[2′,3′: 4,5]pyrrolo[1,2-d][1,2,4]triazolo[3,4-f][1,2,4]triazines 10a-c. Hydrazones 11a-c were formed from 3a-c and 5-[3-(trifluoromethyl)phenyl]furan-2-carboxaldehyde. The effect of microwave irradiation on some condensation reactions was compared with “classical” conditions. The results showed that microwave irradiation shortens the reaction time while affording comparable yields.
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