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EN
The methane to methanol conversion via esterification is an interesting method which makes it possible to eliminate the otherwise necessary phase of obtaining synthesis gas. On the basis of laboratory investigations mass balances for this process were determined. Preliminary assessment of the way of conducting the process and possibilities of practical applications of this technology was also made. It was pointed out that regardless of any possible modifications of methane to methanol conversion via esterification redundant sulfuric acid will always be produced during ester hydrolysis. Production of methanol from methane using this method can only be done when it is combined with producing other substances, which needs using H2SO4.
EN
Three-dimensional (3D) computer models of Ag-Sb-Sn and MgO-Al₂O₃-SiO₂ systems T-x-y diagrams have been designed. For the metal system two versions of 3D model of its phase diagram have been constructed according to the contradictions in the temperature intervals of the compound Sb₂Sn₃ stability. Possibilities of the analysis of the stages of crystallization and prediction of microstructural constituents with the aid of the calculation of vertical mass balance diagrams are demonstrated on the basis of the 3D computer model for the oxide system.
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