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EN
The results of the corrosion test for washing and cutting fluids used in the process of gear-shafts production are presented. The test has been performed according to the DIN 51360-2 (Ford-test) and the PN-92/M-55789 procedures. Three cutting fluids and three washing fluids were chosen and their solutions in tap water (used in practice in the company) were investigated. On the basis of the obtained results it has been stated that the lower the fluid concentration, the stronger corrosion is developed. The concentrations recommended by the producer in the case of cutting fluids are properly chosen. For washing fluids two regions of concentration have been evaluated. The concentration recommended for rinsing is too low for protection against corrosion, while higher concentrations, for the washing process, are properly chosen, and corrosion did not occur.
EN
This paper presents an analysis of the corrosion hazard in the burner belt area of waterwalls in pulverised fuel (PF) boilers that results from low-NOx combustion. Temperature distributions along the waterwall tubes in subcritical (denoted as SUB) and supercritical (SUP) boilers were calculated and compared. Two hypothetical distributions of CO concentrations were assumed in the near-wall layer of the flue gas in the boiler furnace, and the kinetics of the waterwall corrosion were analysed as a function of the local temperature of the tubes. The predicted rate of corrosion of the boiler furnace waterwalls in the supercritical boilers was compared with that of in the subcritical boilers.
EN
Corrosion of metals is a serious environmental problem and has been given much attention in the oil and gas industries. In several industrial processes (acid cleaning and etching, removal of rust and scale), metal surfaces are often made to come in contact with acids. In the present study, an attempt was made to examine Poupartia birrea (P. birres) back extract as a potential green corrosion inhibitor for mild steel in a 0.5 M H2SO4 medium, using the weight loss determination method. The results of our work indicate that highest inhibition efficiency exhibited by Poupartia birrea is 70%. The inhibiting effect of the studied extract could be attributed to the presence of phytochemical constituents present in the extract that are adsorbed on the surface of the mild steel. The plant extract can, hence, be considered as being eco-friendly and an effective green corrosion inhibitor for mild steel exposed to an acid medium.
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issue 4
865-869
EN
SO3-Ph-BTBP is a hydrophilic tetra-N-dentate ligand proposed for An(III)/Ln(III) separation by solvent extraction, and a candidate for use in future advanced reprocessing schemes such as GANEX and SANEX. We present the first study of the effect of SO3-Ph-BTBP on the corrosion behavior of stainless steels. Specifically, studies have been performed using steels and conditions equivalent to those found in relevant nuclear reprocessing flow sheets. SO3-Ph-BTBP has been shown to have little effect on either steel passivation or reductive dissolution. However, if driven cathodically into a region of hydrogen evolution at the electrode surface or conversely anodically into a region of transpassive dissolution, observed currents are reduced in the presence of SO3-Ph-BTBP, suggesting corrosion inhibition of the steel potentially through weak absorption of a SO3-Ph-BTBP layer at the metal-solution interface. The lack of any observed corrosion acceleration via complexation of Fe3+ is surprising and has been suggested to be due to the slow extraction kinetics of SO3-Ph-BTBP as a result of a requirement for a trans- to cis-conformational change before binding.
EN
Constituents of the ethanol extract of Sida acuta (SA) leaves were investigated by phytochemical, GC-MS and FTIR studies and its corrosion inhibition effects on mild steel was studied in 1 M HCl and 0.5 M H2SO4 solutions, using gravimetric and electrochemical methods of corrosion monitoring. The surface morphology of the mild steel surface before and after corrosion was also assessed using SEM imaging. The phytochemical, GC-MS and FTIR results revealed that SA contains carbonyl groups, aromatic rings, and double bonds that make it a prospective corrosion inhibitor for mild steel. Moreover, gravimetric results indicated that SA is an effective additive for the corrosion of mild steel at all the concentrations studied. Finally, the electrochemical results showed that SA inhibited both the anodic and cathodic half reactions by the adsorption of the extract constituents on the mild steel surface; this was further confirmed by the SEM investigations.
EN
Experimental investigations have been performed to determine the effects of nicotiana tobaccum (tobacco) extract additive on the electrodeposition of zinc on mild steel in acid chloride solution. The experiments were performed under different plating time, different additive concentrations and fixed pH conditions. Zinc electrodeposition on mild steel was performed using a DC - supply at defined operating parameters. The surface of the plated steel was examined using scanning electron microscopy (SEM); and Energy Dispersive Spectroscopy (EDS) for the surface elemental composition analysis. Different surface characteristics were obtained depending upon the concentration of the additive and the plating time. The corrosion resistance of the plated surface was also determined by a gravimetric method. The quality of the electro-deposition of zinc was good as indicated by the microstructural morphology of the plated surface except for the few porosities observed. The electrodeposition process was sensitive to the changes in the additive concentration and plating time. Any variation in the plating parameter produced an entirely new and different surface morphology.
12
71%
EN
New binary lanthanum-aluminum triphosphates were synthesized by thermal-condensation method from H3PO4, La2O3 and Al(OH)3. These pigments could be potentially used as special inorganic pigments; their corrosion-inhibition properties were widely studied. Synthesis conditions were determined on the basis of DTA and TG measurements. The products were also characterized by X-ray diffraction analysis. Physical properties - density by pycnometric method, particle size distribution, oil number and critical pigment volume concentration (CPVC), pH and specific conductivity of their aqueous extracts were also determined. [...]
EN
Herein, the optimization of inhibitive action of the ethanol extract of oil from Picralima nitida leaves, towards acid corrosion of zinc, was tested using weight loss and thermometry methods. We found that the extract acts as a good corrosion inhibitor for zinc corrosion in 0.1 M HCl solutions. The inhibition action of the extract was discussed in view of Langmuir adsorption isotherm. This revealed that spontaneous processes govern the adsorption of the extract on zinc surface. Herein, the inhibition efficiency (IE) increases in line with corresponding increase in extract concentration. The temperature effect of the corrosion inhibition on the IE was also studied. This indicated that the presence of the extract increases the needed activation energy of the corrosion reaction. Furthermore, in our work, an optimal inhibition efficiency IE (%) of 86.78 was obtained at optimum inhibitor concentration of 1.2 gl-1, optimum temperature and time of 313 k and 8 hrs, respectively. From the calculated thermodynamic parameters, it can be said, then, that Picralima nitida extract provides good protection to zinc against pitting corrosion in chloride ion containing solutions.
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