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Complexation of poly(ethylene glycol) with poly(ethyl methacrylate-co-N-vinyl-2-pyrrolidone) gel based on hydrogen bonds

100%
Liu G.
Polish Journal of Chemical Technology
|
2013
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vol. 15
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issue 3
85-90
EN
The complexes of poly(ethyl methacrylate-co-N-vinyl-2-pyrrolidone) (P(EMA-co-VP)) gel with poly- (ethylene glycol) (PEG) stabilized by the hydrogen bonds were prepared. It was found that both the concentration and the molecular weight of PEG have a strong effect on the P(EMA-co-VP) gel. When PEG was introduced into the P(EMA-co-VP) gel, the glass transition temperatures (Tg) of the complexes decreases with the decreasing of PEG molecular weight. In such a system, the maximum molecular weight of PEG required for the complex formation is no more than 2000, and P(EMA-co-VP)/PEG complexes are a homogeneous amorphous phase, which was studied by FTIR, XRD, TEM, and DSC.
2
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Complex lag synchronization of two identical chaotic complex nonlinear systems

100%
Mahmoud E., Abualnaja K.
Open Physics
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2014
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vol. 12
|
issue 1
63-69
EN
Much progress has been made in the research of synchronization for chaotic real or complex nonlinear systems. In this paper we introduce a new type of synchronization which can be studied only for chaotic complex nonlinear systems. This type of synchronization may be called complex lag synchronization (CLS). A definition of CLS is introduced and investigated for two identical chaotic complex nonlinear systems. Based on Lyapunov function a scheme is designed to achieve CLS of chaotic attractors of these systems. The effectiveness of the obtained results is illustrated by a simulation example. Numerical results are plotted to show state variables, modulus errors and phase errors of these chaotic attractors after synchronization to prove that CLS is achieved.
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THE EFFECT OF POLOXAMER 407 ON THE PROPERTIES OF HYDROPHILIC GELS CONTAINING LACTIC ACID COMPLEXED WITH CHITOSAN

75%
Małolepsza-Jarmołowska K.
Progress on Chemistry and Application of Chitin and its Derivatives
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2010
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vol. 15
143 - 148
EN
Anatomical and physiological conditions in the vagina do not facilitate easy application of the drug neither its maintenance on the site of application. Insufficient duration of the drug’s contact with vaginal mucosa does not provide adequate pH conditioning the physiological biocenosis of the organ. Gels containing lactic acid complexed with chitosan at a stechiometric ration 1:1 and 2:1 and 5 - 25% content of PEG-200 are able to move from 25 to 30 cm. Higher concentrations of the poloxamer 407: 23 and 25% result in the movability of 20 to 24 cm. The addition of 20 – 25% poloxamer 407 increases the pH to 4.55 to 5.30 for 1:1 gels and 4.00 to 4.85 for 2:1 gels. The investigations showed that the addition of a thermosensitive polymer increases the adhesive properties of the investigated gels. Rheological investigations revealed an increase in the dynamic viscosity of preparations containing poloxamer 407 in comparison to the reference gels.
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