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  1. 1 Open Chemistry

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  1. 1 2006

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  1. 1 Kutkin A.

  2. 1 Platonov M.

  3. 1 Terent’ev A.

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A new oxidation process. Transformation of gem-bishydroperoxides into esters

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Terent’ev A., Platonov M., Kutkin A.
Open Chemistry
|
2006
|
vol. 4
|
issue 2
207-215
EN
A new oxidation process has been found where α,ω-dicarboxylic acid esters and ω-hydroxycarboxylic acid esters are formed on heating gem-bishydroperoxides in alcohol in the presence of BF3·Et2O. By addition of H2O2 to this reaction α,ω-dicarboxylic acid esters are formed almost selectively.
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