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Open Physics
|
2008
|
vol. 6
|
issue 2
332-343
EN
A new approach for determination of refractive index dispersion n(λ) (the real part of the complex refractive index) and thickness d of thin films of negligible absorption and weak dispersion is proposed. The calculation procedure is based on determination of the phase thickness of the film in the spectral region of measured transmittance data. All points of measured spectra are included in the calculations. Barium titanate thin films are investigated in the spectral region 0.38–0.78 μm and their n(λ) and d are calculated. The approach is validated using Swanepoel’s method and it is found to be applicable for relatively thin films when measured transmittance spectra have one minimum and one maximum only.
EN
The effective piezoelectric coefficients of BaTiO₃ ferroelectric films epitaxially grown on different single crystal substrates with finite thickness have been theoretically analyzed. The effective longitudinal converse piezoelectric coefficients d₃₃ of film and "film-substrate" heterostructure all monotonously increased with increase of the film thickness fraction k, and the latter is always larger than the former at the range of 0 < k < 1. Meanwhile, we also found that the effective piezoelectric coefficients d₃₃ were affected by the substrates due to different elastic constants. These results show that the elastic deformation and clamping effect of substrate have significant impacts on the piezoelectric behavior of bilayer heterostructure.
EN
The relaxation processes and the properties of polymer/ceramic nanocomposites have been studied by the 1H nuclear magnetic resonance methods. Nanocomposites of poly(ethylene terephthalate) PET and poly(phenylene sulfide) PPS with 0.25, 2.5 and 5% wt. barium titanate BT were prepared using a twin screw extruder and injection moulding machine. The spin-lattice relaxation time T1, second moment M2 and the motional parameters as e.g. the activation energies in the nanocomposites were investigated.
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