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Efficient Lewis acid-assisted Brønsted acid (LBA) catalysis in the iron-catalyzed Friedel-Crafts alkylation reaction of indoles

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Jiang Z.-Y., Wu J.-R., Li L., Chen X.-H., Lai G.-Q., Jiang J.-X., Lu Y., Xu L.-W.
Open Chemistry
|
2010
|
vol. 8
|
issue 3
669-673
EN
Lewis acid-assisted Brønsted acid (LBA) catalysis was proposed for the iron-catalyzed Friedel-Crafts alkylation of indoles with chalcones. This proposal was supported by the ESI-MS and cyclic voltammetry. The addition of acac to the iron-catalyzed Friedel-Crafts alkylation of indoles with chalcones created a powerful catalytic system, which makes the alkylation reactions occur easily under mild conditions. [...]
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