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Simultaneous displacement of a nitro group during coupling of diazotized o-nitroaniline with phenols

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Farkas R., Törincsi M., Kolonits P., Fekete J., Alonso O., Novak L.
Open Chemistry
|
2010
|
vol. 8
|
issue 2
300-307
EN
During the diazo-coupling reaction, nucleophilic displacement of a nitro group was also observed. This was the main reaction (1→7) when the starting amine bore either a chlorine or methoxy group at the para position (1b–c). The newly prepared compounds (7) might serve as convenient building blocks in synthesis of some heterocycles. [...]
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