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L-alaninium perrhenate: crystal structure and non-linear optical properties

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Rodrigues V., Costa M., Gomes E., Isakov D., Belsley M.
Open Chemistry
|
2014
|
vol. 12
|
issue 10
1016-1022
EN
The crystal structure and non-linear optical properties of L-alaninium perrhenate, C3H8NO2+ ReO4 −, are reported. The protonated amino acid and the perrhenate anion have their usual geometries. The three-dimensional hydrogen-bonded network can be seen as a stacking of layers parallel to the (100) planes. Each layer is formed by chains of alternating positive and negative ions along the b and c axes. Hydrogen bonding of adjacent layers forms alternating chains along the a axis. A high damage threshold and a second-harmonic generation efficiency three times that of KDP make this new material potentially useful in non-linear optics.
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