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  1. 1 Open Chemistry

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  1. 1 2010

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  1. 1 Hafez M.

  2. 1 Shoukry A.

  3. 1 Shoukry M.

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Kinetics of base hydrolysis of α-amino acid esters catalyzed by palladium(II) piperazine complex

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Shoukry A., Shoukry M., Hafez M.
Open Chemistry
|
2010
|
vol. 8
|
issue 4
797-805
EN
The kinetics of base hydrolysis of glycine, histidine, and methionine methyl esters in the presence of [Pd(pip)(H2O)2]2+ complex, where pip is piperazine, is studied in aqueous solutions, at T = 25°C, and I = 0.1 mol dm−3. The rate of ester hydrolysis for glycine methyl ester is studied at different temperature and dioxane/water solutions of different compositions. The kinetic data are fit under the assumption that the hydrolysis proceeds in one step. The activation parameters for the base hydrolysis of the complexes are evaluated [...]
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