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  1. 1 Capozzolo L.

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Sulfoxides in the allylation of aldehydes in the presence of silicon tetrachloride and allyltributylstannane

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Massa A., Capozzolo L., Scettri A.
Open Chemistry
|
2010
|
vol. 8
|
issue 6
1210-1215
EN
SiCl4 can be conveniently activated by catalytic amounts of dimethyl sulfoxide or other readily-available sulfoxides for the allylation of aromatic, hetero-aromatic and unsaturated aldehydes in the presence of allyltributyl stannane. Chiral aryl methyl sulfoxides have been used to develop asymmetric allylation methods, as well as probe the aldehyde substrate scope.
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