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EPR Characteristics of Activated Carbon for Hydrogen Production by the Thermo-Catalytic Decomposition of Methane

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Więckowski A., Najder-Kozdrowska L., Rechnia P., Malaika A., Krzyżyńska B., Kozłowski M.
Acta Physica Polonica A
|
2016
|
vol. 130
|
issue 3
701-704
EN
The electron paramagnetic resonance (EPR) method was used to characterize samples of activated coal before and after reactions of the catalytic decomposition of methane and ethanol at temperatures of 1023 K (750°C), 1123 K (850°C) and 1223 K (950°C). The EPR parameters: spectroscopic splitting factor g, peak-to-peak linewidth ΔBₚₚ, and spin concentration c were measured. During the ethanol-assisted catalytic decomposition of methane carbon-located-spin radicals are partially transformed into oxygen-located-spin radicals.
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