Multilayers of titanium oxide on conductive glasses (silica, covered with indium/tin and tin oxides) were obtained by different methods (from suspension, by sol-gel, by vacuum sputtering). X-ray diffraction and positron annihilation depth-resolved characterization of these samples are presented. The data allow us to determine optimal deposition parameters, in order to obtain the anatase phase, important in practical applications in photoelectrochemical cells.
Electrochemical properties of a zinc/polyvinyl alcohol-potassium hydroxide/carbon cell have been investigated. In this cell, PVA-KOH gel has been used as an electrolyte with PVA/KOH wt.% ratio of 60:40, while zinc and carbon rods served as electrodes. The cylindrical glass vessel of length 3.0 cm and of diameter 2.0 cm has been used as a cell compartment. The current-voltage characteristics and open circuit voltage-time, charge voltage/current-time and discharge voltage/current-time studies have been done. The open circuit voltage has been observed for 160 h. It has been found that the cell shows stability and is rechargeable, too.
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