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Supercrystallization of NaCl from Solution Irradiated by Soft X-Rays

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Janavičius A., Purlys R., Rinkūnas R.
Acta Physica Polonica A
|
2013
|
vol. 123
|
issue 4
777-781
EN
It was found that irradiation of a water solution of NaCl with the diffractometer DRON3-M (Russian device) had a large influence on two-step processes of crystallization. The irradiation in the first stage of crystallization of the solution produces metastable radicals of water and excited seeds, which stimulate a very fast crystallization after switching off irradiation. After the crystals reach a sufficient size, the crystal growth can be explained by creation of vacancy-interstitial pairs in the growing crystal due to irradiation. The increase of linear dimensions of the growing irradiated crystals is proportional to the square root √t of crystallization time because most important place in crystallization takes the ions diffusion by irradiated vacancies.
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