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  1. 1 Sisak A.

  2. 1 Szalontai G.

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Formation and multinuclear magnetic resonance investigation of silylammonium tetracarbonylcobaltate contact ion pairs

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Sisak A., Szalontai G.
Open Chemistry
|
2006
|
vol. 4
|
issue 2
299-316
EN
Silylcobalt tetracarbonyls were reacted with various amines (B) in non-polar solvents to form silylammonium tetracarbonylcobaltate contact ion pairs formulated as [BSiR3+, −Co(CO)4]. The compounds were characterized by IR and multinuclear magnetic resonance spectroscopy both in solution and in solid state. Their properties are analogous to the known ion pairs [BH+, −Co(CO)4] and to amine adducts of halosilanes as well.
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