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EN
In this work two Co_{53.5}Fe_{10}X_{5.5}B_{31} (X = Ta, W) alloys were synthesized from high purity (≥99.9%) powder elements by means of mechanical alloying. In case of Ta-addition, mechanical alloying resulted in formation of two component material with nanocrystalline phase embedded in amorphous matrix. On the other hand, substitution of Ta by W retards partial amorphization induced by mechanical alloying. High pressure-temperature stability of both alloys was monitored using in situ energy dispersive X-rays.
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EN
Metallic glasses, in contrast to its crystalline counterparts, exhibit unique mechanical and structural properties, which make them attractive for practical applications. Especially Ni-Ti-Zr metallic glass is a promising alloy for micromechanical systems because of its known shape memory properties. Shape memory effect is connected with structural phase transformation. In this paper, the ambient-temperature-structure of Ni-Ti-Zr metallic glass is investigated using transmission electron microscopy and synchrotron X-ray diffraction, the surface and chemical analysis is documented using scanning electron microscopy. Thermal stability of the alloy has been determined using differential scanning calorimetry.
EN
The Ni-Ti-Zr metallic glasses are due to their known shape memory properties promising alloys e.g. for micromechanical applications. In this paper structure and structure stability of one particular alloy Ni₆₀Ti₂₅Zr₁₅ at.% were examined by means of X-ray diffraction and transmission electron microscopy while magnetic properties were ascertained by vibrating-sample magnetometer with maximal applied field of 100 kA/m in the temperature range of 300-1073 K.
EN
Ribbons of composition Co₄₉Ni₂Ga₃₀ have been prepared by melt-spinning method. X-ray diffraction investigation revealed single phase with B2 structure at room temperature. However, analysis of magnetization dependence of temperature suggests phase transition in the range 150-250 K. Resistivity measurements revealed similar transition with shift to higher temperatures in the presence of magnetic field.
EN
We present the study on production and structural, electric and magnetic properties of superconductive Ni₂NbSn Heusler alloy. The sample has been produced by melt-spinning method using tangential speed of copper wheel 20 m/s. Polycrystalline structure has been obtained showing single phase with B2 disorder with lattice constant a=6.1654 Å. Resistance measurement shows superconductive behavior with critical temperature close to 5 K. Magnetic measurements also exhibit diamagnetic contribution from superconductive phase. Additionally, the ferromagnetic state has been observed below 20 K, which points to the coexistence of magnetic and superconducting state.
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