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On Symmetry-Concerted Organometallic Analogues of the Ethylene Dimerization

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Roszak S., Chojnacki H., Balasubramanian K.
Acta Physica Polonica A
|
1995
|
vol. 87
|
issue 6
965-969
EN
A theoretical study of the C_{2v} symmetry-concerted reaction is presented for the addition of ethylene and molybdenum dimer. The potential curves corresponding to different self-consistent field closed shell configurations are studied. A comparison of ethylene dimerization and ethylene-Mo_{2} formation reactions indicates close similarities and applicability of the Woodward-Hoffmann model, developed originally for olefins, to organometallics.
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